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SSRN 2025年

作者： Liu, Hang Li, Yang Huang, Heng Zhou, Zhifu Wu, Wei-Tao Wei, Lei Lyu, Jizu Hu, Chengzhi Li, Yubai Song, Yongchen Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education Dalian University of Technology Dalian116024 China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi’an710049 China School of Mechanical Engineering Nanjing University of Science and Technology Nanjing210094 China Department of Mechanical and Energy Engineering Southern University of Science and Technology Shenzhen518055 China School of Mechanical Engineering Guangdong Ocean University Zhanjiang524088 China

The gas diffusion layer (GDL) of proton exchange membrane fuel cells (PEMFCs) is a critical component for the transport of reactants. The efficiency of reactant gas transport remains a major technical challenge in the field today. The anisotropic structure of the GDL gives rise to substantial variations of gas diffusion as well as permeability in different directions. The study employs X-CT technology to obtain the actual GDL’s geometry, aiming to investigate a spatial structure at the microscale and its gas transport characteristics. CFD method is used to simulate and study the gas diffusivity and gas permeability of GDL with four different thicknesses. The numerical simulation results show the diffusivity and permeability in the Through-plane (TP) direction are lower than those in the In-plane (IP) direction. Moreover, the effective diffusion coefficient decreases with increasing thickness, but is also dependent on the solid fibre structure of GDL. Horizontal alignment of the carbon fibers and the disc-shaped adhesive contributes to the anisotropy between the TP and IP directions, resulting in anisotropic gas transport. The purpose of the study is to supply critical references for manufacturing techniques and optimization of gas transport in GDLs. © 2025, The Authors. All rights reserved.

关键词： Gas permeability

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Recent advances in nanoporous graphene membrane for gas separation and water purification

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Science Bulletin 2015年第21期60卷 1807-1823页

作者： Chengzhen Sun Boyao Wen Bofeng Bai State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University

Graphene is a one-atom-thick sheet of graphite comprising sp2-hybridized carbon atoms arranged in the hexagonal honeycomb lattices. By removing the honeycomb lattices and forming nanopores with specific geometry and size, nanoporous graphene has been demonstrated as a very high-efficiency separation membrane, due to the ultrafast molecular permeation rate for its one-atom thickness. This review focuses on the recent advances in nanoporous graphene membrane for the applications of gas separation and water purification, with a major emphasis on the molecular permeation mechanisms and the advanced fabrication methods of this state-of-the-art membrane. We highlight the advanced theoretical and experimental works and discuss the gas/water molecular transport mechanisms through the graphene nanopores accompanied with theoretical models. In addition, we summarize some representative membrane fabrication methods, covering the graphene transfer to porous substrates and the pore generation. We anticipate that this review can provide a platform for understanding the current challenges to make the conceptual membrane a reality and attracting more and more attentions from scientists and engineers.

关键词： Nanoporous graphene Gas separationWater purification Molecular permeationmechanism Membrane fabrication

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A wall-temperature-independent heat transfer model and dominant dimensionless numbers for supercritical CO 2 in vertical upward flow

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The Journal of Supercritical Fluids 2025年 224卷

作者： Zhenghui Hou Haifan Liao Kuang Yang Shaozhe Bai Xinjiang Fan Chaofan Yang Haijun Wang State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an 710049 China

The heat transfer coefficient is a critical parameter for the design and optimization of supercritical carbon dioxide (sCO₂) heat exchange systems. Based on 20723 data points collected from 22 published studies, existing heat transfer correlations are evaluated, and a new model with improved stability and predictive accuracy is developed. Current correlations for upward vertical sCO₂ flow typically include wall-temperature-dependent parameters, which often lead to issues such as non-uniqueness or the absence of solutions during wall temperature prediction, along with limited accuracy. To address these issues, this study integrates the Buckingham Pi theorem and constructs a wall-temperature-independent heat transfer model using a dimensionless neural network. This approach avoids the problems of multiple or no solutions and achieves high predictive performance, with mean absolute relative errors of 2.83 % for wall temperature and 5.81 % for Nusselt number predictions. Furthermore, the active subspace method is employed to identify four dominant dimensionless groups governing the heat transfer process. These groups can be decomposed into products of commonly known dimensionless numbers. During this process, a new dimensionless number—the buoyancy generation ( BG ) number—is proposed and defined. This study leverages data-driven dimensional analysis to explore key influencing parameters and dominant dimensionless numbers for supercritical heat transfer, offering new insights into the underlying physical mechanisms.

关键词： Electric heating

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Thermal and hydraulic performance of molten salt steam generation system under varying operating conditions in concentrating solar power plants

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Case Studies in Thermal engineering 2025年 72卷

作者： Jiaming Tian Bo Ren Yiran Duan Biao Li Yueshe Wang State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an 710049 China

To conduct the thermal transport characteristics and operational stability of the steam generation system (SGS) under partial load conditions in concentrating solar power (CSP), a real-scale shell-and-tube steam generator hydrodynamics predictive model is developed. This model integrates lumped parameter methods with the finite volume method to account for heat transfer and phase change. Additionally, in accordance with the prevailing water circulation mode in the CSP plant, a typical model of the natural circulation system is established, while optimal stable operating points of the maximum circulation mass flow rate under varying operating conditions are determined. The results indicate that the inherent stability of the generator strongly lies in the dynamic compromise between its thermodynamic and hydrodynamic characteristics. Under high load conditions, the natural circulation mode demonstrates excellent flow stability. Operating at lower operating pressures results in greater circulation flow and a heightened sensitivity to phase changes. Under system pressures of 13.76, 11.08, 8.39, and 6.71 MPa, the recommended circulation ratios are determined to be 5.38, 7.86, 11.95, and 16.07, respectively. Furthermore, the stability of the circulation curve is optimized by adjusting the structural dimensions of the steam generator. The sensitivity to evaporation capacity and heat exchanger effectiveness is assessed.

关键词： Molten salt storage Steam generator Natural circulation mode Concentrating solar power

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Curvature-property coupling governed heat transfer deterioration in supercritical helically coiled tubes: Mechanistic insights and mitigation strategies via structural parametrization

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International Journal of Thermal Sciences 2025年 215卷

作者： Chang, Fucheng Xin, Jiaxing Wu, Xiaoyi Li, Liwei Li, Huixiong Zhu, Yanlin National Key Lab of Aerospace Power System and Plasma Technology School of Mechanical Engineering Xi'an Jiaotong University Xi'an 710049 China China Special Equipment Testing and Research Institute Beijing 100029 China State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi'an Jiaotong University Xi'an 710049 China Shanghai Nuclear Engineering Research & Design Institute Co. Ltd Shanghai 200233 China

The unique thermo-hydrodynamic coupling phenomena in the helically coiled tube (HCT) handling supercritical fluids present both opportunities and challenges for next-generation compact heat exchangers. While the pronounced thermophysical property variations near pseudo-critical temperatures (T_pc) and curvature-induced secondary flows synergistically enhance heat transfer coefficient (HTC), their nonlinear coupling mechanisms may unexpectedly provoke severe heat transfer deterioration (HTD). Through systematic numerical investigations, this study reveals that circumferential wall temperature inhomogeneity (CWTI) exhibits an inverted N-shaped evolution, providing valuable insights for thermal homogenization design near T_pc. The secondary flow Reynolds number (Se), quantifying secondary flow intensity, shows a monotonic increase with decreasing coil diameter (D_c) or inner diameter (D_i), reaching saturation in high-enthalpy regions. Notably, CWTI demonstrates non-monotonic behavior, achieving minimum values near T_pc before manifesting distinct rebound characteristics near T_pc conditions. Parametric analysis establishes that: (1) Elevating heat flux (q) increases Se, reducing D_c boosts it by 50.3 %, and decreasing D_i raises it by 60.0 %. (2) HTD predominantly initiates at the outer wall under high-q conditions, with D_c reduction achieving HTD suppression and 26.9 % enhancement in the local HTC;(3) Reducing the D_i results in a reduction of maximum CWTI by 22.5 %–28.6 %, suggesting that structural parametrization effectively mitigates wall temperature non-uniformity, thus suppressing the HTD. While centered on supercritical water, the dimensionless scaling relationships demonstrate extendibility to other media, with the curvature-property coupling mechanism both elucidating fundamental interactions and guiding robust heat exchanger design. © 2025 Elsevier Masson SA

关键词： Heat transfer deterioration Helically coiled tube Structural parametrization Supercritical fluid Thermo-hydrodynamic coupling

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A review of engine application and fundamental study on turbulent premixed combustion of hydrogen enriched natural gas

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Science China(Technological Sciences) 2014年第3期57卷 445-451页

作者： WANG JinHua WEI ZhiLong ZHANG Meng HUANG ZuoHua State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University

The application and fundamental study on turbulent premixed combustion of hydrogen enriched natural gas is reviewed in this *** include the combustion characteristics of direct injection engine fueled with hydrogen enriched natural gas,visualization study of direct injection combustion of hydrogen enriched natural gas using a constant volume vessel,and the fundamental study of turbulent premixed combustion of hydrogen enriched natural *** effect of additional hydrogen on the combustion process of natural gas engine is investigated from the fundamental view of the interaction between combustion reaction and turbulent flow.

关键词： natural gas hydrogen direct injection combustion turbulent premixed combustion OH-PLIF engine

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Corrigendum to “Experimental study on flow boiling and circumferential non-uniform heat transfer characteristics in helically-coiled tube under coupled heat transfer conditions” [Appl. Therm. Eng. 258(Part C) (2025) 124844]

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Applied Thermal engineering 2025年 261卷

作者： Hengyuan Wang Qiyu Xuan Hailin Lei Xi Li Zhibin Li Huixiong Li State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Xi’an 710049 China

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Study on thermo-fluid-chemical coupling simulation and characteristic fields evolution during in-situ pyrolysis of tar-rich coal

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International Journal of Heat and Fluid flow 2025年 116卷

作者： Meijing Chen Yongbo Du Chang’an Wang Yujie Hou Tianlin Yuan Liujun Chang Lei Deng Defu Che State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Xi’an 710049 China

Underground in-situ pyrolysis of tar-rich coal is an effective approach to expand the supply channels of oil and gas while ensuring energy security, and it has currently aroused wide attention in the academic community. The coupling of multiple interdependent physical fields causes the in-situ pyrolysis process and related phenomena. However, existing studies usually only have focused on a single process. The study proposed a three-dimensional (3D) model for the in-situ pyrolysis of tar-rich coal employing external high-temperature fluids. Numerical simulation was used to achieve the transient calculation of the coupling model of chemical reaction, fluid flow, and heat transfer. The impacts of medium type, medium temperature, inlet rate, well patterns, and the number of horizontal fractures were investigated by characterizing the temperature and concentration fields. The results indicate that, under the basic working condition, the pyrolysis reaction of tar-rich coal in the formation has been completed after ∼28.5 months of heat injection. Both N 2 and CO 2 are heat carriers with greater advantages in heat transfer as compared to H 2 O (g). The threshold of injection rate is 5 m·s −1 . The heat transfer effect of coal seams with 4 injection wells is obviously better than that of 1 and 2 injection wells. The number of 3 horizontal fractures is superior to 1 and 2 fractures, which can effectively enhance heat transfer and promote the thermal decomposition. The present study has emphatically investigated the evolution of characteristic fields of tar-rich coal seams under thermo-fluid-chemical coupling conditions during the in-situ pyrolysis process, providing substantial reference significance to guide the in-situ conversion mining.

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Constructing electron transport channel of SnO2/BaSO4 on g-C3N4 for enhanced visible-light-driven photocatalytic H2 production

Materials Today Catalysis

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Materials Today Catalysis 2025年 9卷

作者： Dong, Gongyue Guo, Xiaojuan Cheng, Cheng Chen, Feng Zhang, Jinfeng Du, Yanping Meng, Wei Liu, Maochang Shi, Jinwen International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China Guangdong Provincial Key Laboratory of Multi-energy Complementary Distributed Energy Systems Dongguan University of Technology Dongguan523808 China School of Engineering Lancaster University LancasterLA1 4YW United Kingdom Gansu Company PipeChina Lanzhou730060 China Hunan Provincial Key Lab of Dark Tea and Jin-Hua Department of Material & Chemical Engineering Hunan City University Yiyang413000 China

Graphitic carbon nitride (g-C3N4) is confronted with the issue of poor utilization of photogenerated charge carriers, thereby leading to limited performance of photocatalytic hydrogen (H2) production, which restricts its potential application. Herein, the electron transport material SnO2/BaSO4 was synthesized to integrate with g-C3N4 for addressing the above problem. Various characterizations were conducted to investigate the g-C3N4-SnO2/BaSO4 photocatalyst, and it demonstrated that photogenerated electrons from g-C3N4 expeditiously migrate to SnO2/BaSO4 nanoparticles, which markedly hindered photogenerated carriers’ recombination. Subsequently, the g-C3N4-SnO2/BaSO4 photocatalyst demonstrated promoted photocatalytic H2 production at a rate of 14.2 μmol h−1 under visible-light illumination, which was 2.5 times higher than that of pristine g-C3N4. © 2025 The Authors

关键词： Barium sulfate

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ȮH insights into the interaction of hydrogen-rich methane and water: Laser absorption experiments and chemical kinetics

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Combustion and Flame 2025年 278卷

作者： Xin Zhang Zilong Feng Congjie Hong Wuchuan Sun Zuohua Huang Yingjia Zhang State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an 710049 PR China

Flue gas recirculation and steam injection are employed in hydrogen-rich gas turbines to stabilize fuel reactivity and improve cycle efficiency, introducing high water vapor content into the combustion chamber and thereby necessitating an investigation of water-fuel interactions at elevated temperatures. This study employed UV laser absorption diagnostics behind reflected shock waves to conduct in situ measurements of the ȮH concentration time-histories during the oxidation of CH 4 /H 2 /H 2 O/O 2 /Ar mixtures at pressures of approximately 1.3, 5.0, and 15.2 atm and temperatures ranging from 1225 to 1888 K with varying hydrogen blending and water addition ratios. The absorption lineshapes of the ȮH R 1 (5) transition in the A-X(0,0) vibronic band were characterized after broadening and shifting in Ar at different pressures, with diagnostic center wavelengths set at 306.6868 nm (1.3 atm), 306.6874 nm (5.0 atm), and 306.6886 nm (15.2 atm), respectively. The obtained ȮH concentration time-history data were compared in detail with predictions from eight representative reaction kinetic models, and the predictive capability of the models for ȮH behavior was quantitatively assessed using the error function method. NUIGMech1.1 exhibited superior performance in predicting ȮH behavior and was subsequently selected for kinetic analysis to elucidate stage-specific micro-mechanisms and identify key reactions driving the concentration evolution. The activating effect of H 2 on ȮH behavior during CH 4 oxidation was investigated. Results indicate that higher hydrogen levels intensify hydrogen-related reaction pathways, expanding the radical pools (H, ȮH, and Ö), thereby promoting fuel consumption through Ḣ-atom abstraction reactions. Additionally, by introducing weak collision H 2 O* and inert H 2 O**, the thermodynamic and kinetic effects of water were distinguished. The results show that under the current conditions, H 2 O primarily affects ȮH behavior through direct participatio

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