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On the spreading behavior of a droplet on a circular cylinder using the lattice Boltzmann method

Chinese Physics B 2024年第6期33卷 434-443页

作者：杨帆金虎戴梦瑶 School of Energy and Power Engineering University of Shanghai for Science and TechnologyShanghai 200093China Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering Shanghai 200093China

The study of a droplet spreading on a circular cylinder under gravity was carried out using the pseudo-potential lattice Boltzmann high-density ratios multiphase model with a non-ideal Peng–Robinson equation of state. The calculation results indicate that the motion of the droplet on the cylinder can be divided into three stages: spreading, sliding, and *** contact length and contact time of a droplet on a cylindrical surface can be affected by factors such as the wettability gradient of the cylindrical wall, the Bond number, and droplet size. Furthermore, phase diagrams showing the relationship between Bond number, cylinder wall wettability gradient, and contact time as well as maximum contact length for three different droplet sizes are given. A theoretical foundation for additional research into the heat and mass transfer process between the droplet and the cylinder can be established by comprehending the variable rules of maximum contact length and contact time.

关键词： lattice Boltzmann methods droplet circular cylinder wettability gradient

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Photocatalytic water splitting on BiVO_(4):Balanced charge-carrier consumption and selective redox reaction

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Nano Research 2023年第4期16卷 4568-4573页

作者： Xiangjiu Guan Li Tian Yazhou Zhang Jinwen Shi Shaohua Shen International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong UniversityXi’an 710049China Suzhou Academy of Xi’an Jiaotong University Suzhou 215123China State Key Laboratory for Physical Chemistry of Solid Surfaces College of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005China

Surficial redox reactions play an essential role in photocatalytic water splitting,and are closely related to the surface properties of a specific *** this work,using monoclinic BiVO_(4)decahedral single crystals as a model photocatalyst,we report on the interrelationship between the photocatalytic activity and the surficial reaction sites for charge-carrier *** controlled hydrothermal synthesis,the ratio of{010}to{110}facets on BiVO_(4),which respectively serve as reductive and oxidative sites,is carefully *** results show that superior photocatalytic water oxidation could be obtained on BiVO_(4)decahedrons with a medium ratio of reductive/oxidative sites and that efficient overall water splitting could be achieved via further modification of appropriate cocatalysts in Z-scheme *** excellent photocatalytic performance is attributed to the accelerated selective redox reactions by realizing balanced charge-carrier consumption,which provides insightful guidance for prospering photocatalytic reactions in energy conversion.

关键词： BiVO_(4) photocatalytic water splitting reactive site

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Assisting effect of Al_(2)O_(3) on MnO_(x) for NO catalytic oxidation

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Green Energy & Environment 2021年第6期6卷 903-909页

作者： Denghui Wang Hui Li Qi Yao Shien Hui Yanqing Niu State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power EngineeringXi'an Jiaotong UniversityXi'an710049China

Various Mn-based catalysts for NO oxidation were prepared using MnO_(x)as active compound,while Ti O_(2)and Al_(2)O_(3)were adopted as catalyst *** performance of the catalysts was tested to study the effect of support on Mn-based catalyst *** of the catalysts followed as Mn_(0.4)/Al>Mn_(0.2)/Al>Mn_(0.4)/Ti>Mn_(0.2)/Ti>MnO_(x)>Al_(2)O_(3)on the whole,indicating the synergism of MnO_(x)and Al_(2)O_(3)for NO catalytic *** were analyzed according to characterization *** oxygen on catalyst rather than lattice oxygen was detected as the active oxidizer for NO *** catalyst support,Al_(2)O_(3)provided more sites to carry surface adsorbed oxygen than TiO_(2),resulting in the presence of more active oxygen on Mn O_(x)/Al_(2)O_(3)than on MnO_(x)/TiO_(2).Moreover,MnO_(x)/Al_(2)O_(3)possessed high surface area and pore volume,which greatly benefited the adsorption of NO on catalyst and further favored the oxidation of NO by active *** these advantages helped Mn_(0.4)/Al exhibited the best catalytic efficiency.

关键词： NO catalytic oxidation MnO_(x)/Al_(2)O_(3) NO_(2) Active oxygen

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Concurrently Boosting Activity and Stability of Oxygen Reduction Reaction Catalysts via Judiciously Crafting Fe-Mn Dual Atoms for Fuel Cells

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Nano-Micro Letters 2025年第4期17卷 275-289页

作者： Lei Zhang Yuchen Dong Lubing Li Yuchuan Shi Yan Zhang Liting Wei Chung-Li Dong Zhiqun Lin Jinzhan Su International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong UniversityXi’an 710049People’s Republic of China Department of Physics Tamkang UniversityNew Taipei CityTaiwan 25137People’s Republic of China Department of Chemical and Biomolecular Engineering National University of SingaporeEngineering Drive 4Singapore 117585Singapore

The ability to unlock the interplay between the activity and stability of oxygen reduction reaction(ORR)represents an important endeavor toward creating robust ORR catalysts for efficient fuel ***,we report an effective strategy to concurrent enhance the activity and stability of ORR catalysts via constructing atomically dispersed Fe-Mn dualmetal sites on N-doped carbon(denoted(FeMn-DA)-N-C)for both anion-exchange membrane fuel cells(AEMFC)and proton exchange membrane fuel cells(PEMFC).The(FeMn-DA)-N-C catalysts possess ample dual-metal atoms consisting of adjacent Fe-N_(4)and Mn-N_(4)sites on the carbon surface,yielded via a facile doping-adsorption-pyrolysis *** introduction of Mn carries several advantageous attributes:increasing the number of active sites,effectively anchoring Fe due to effective electron transfer to Mn(revealed by X-ray absorption spectroscopy and density-functional theory(DFT),thus preventing the aggregation of Fe),and effectively circumventing the occurrence of Fenton reaction,thus reducing the consumption of ***(FeMn-DA)-N-C catalysts showcase half-wave potentials of 0.92 and 0.82 V in 0.1 M KOH and 0.1 M HClO_(4),respectively,as well as outstanding *** manifested by DFT calculations,the introduction of Mn affects the electronic structure of Fe,down-shifts the d-band Fe active center,accelerates the desorption of OH groups,and creates higher limiting *** AEMFC and PEMFC with(FeMn-DA)-N-C as the cathode catalyst display high power densities of 1060 and 746 mW cm^(-2),respectively,underscoring their promising potential for practical *** study highlights the robustness of designing Fe-containing dual-atom ORR catalysts to promote both activity and stability for energy conversion and storage materials and devices.

关键词： Doping-adsorption-pyrolysis Dual-atom catalysts Oxygen reduction reaction Fuel cells

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CAPACITY OPTIMIZATION OF ADVANCED ENERGY STORAGE TECHNOLOGIES FOR PEAK SHAVING AND FREQUENCY REGULATION BASED ON ECONOMIC AND CARBON-MITIGATION CO-BENEFIT 37

CAPACITY OPTIMIZATION OF ADVANCED ENERGY STORAGE TECHNOLOGIE...

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37th International Conference on Efficiency, Cost, Optimization, Simulation and Environmental Impact of Energy Systems, ECOS 2024

作者： Nie, Lu Li, Yanxin Gan, You Han, Xiaoqu Wang, Tong Yan, Junjie State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an China Huadian Electric Power Research Institute Co. Ltd. Beijing China

ISBN: (纸本)9798331307660

With the rapid scale-up in popularity of renewable energy sources, the new power system is suffering from enhanced *** order to improve flexibility of new power system and mitigate carbon emission, the integration of thermal power plants with energy storage technologies (ESTs) has gradually become a promising *** a key support for the development of new power system, it is of great significance to investigate the capacity optimization of advanced ***, there was a lack of study related to the capacity optimization of ESTs and the combination revenue patterns of ESTs were seldom *** the present work, a capacity optimization model was established for ESTs operating in combination with thermal power plants on the generating side, including lithium iron phosphate battery (LIPB), vanadium redox flow battery (VRFB), compressed air energy storage (CAES), supercapacitors (SC), and flywheel (FE) with the goal of maximizing the ***, VRFB, and CAES energy storage systems were investigated in the peak shaving (PS) *** co-benefit of ESTs was significant, 30.7-43.2 $/MWh, internal rate of return (IRR) was 12%-20%, and payback period (PP) was 6-11 years when the ratio of ESTs allocation (EAR) for thermal power plants was 2.50%-5.52%.LIPB, VRFB, CAES, SC, and FE were investigated in the frequency regulation (FR) *** co-benefit of ESTs was 51.9-329.3 $/MWh, IRR was 20%-35%, and PP was 3-7 years when the EAR was 0.24%-5.65%.The contribution of carbon mitigation benefit to co-benefit for different ESTs varied substantially, ranging from 6.46% to 82.75%.The ESTs not only offered ancillary service, but also other services when it operated as an independent shared energy storage.A new combination revenue pattern was proposed, under which revenue increased by 35%-55% compared to that of existing *** analysis was performed, in which the cost of energy storage, carbon tax, peak-valley spread, and comprehensi

关键词： flow batteries

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Changing Conditions and Thermodynamic Transient Characterization of Therminol VP-1 Oil-Water Heat Exchanger

Changing Conditions and Thermodynamic Transient Characteriza...

引用

2024 Boao New power System International Forum - power System and New Energy Technology Innovation Forum, NPSIF 2024

作者： Dong, Shuai Zheng, An Wang, Peng Wang, Chaoyang Huaneng Yimin Coal-Power Co. Ltd. Hulunbuir China Xi'an Jiaotong University State Key Laboratory of Multiphase Flow in Power Engineering Xi'an710049 China

ISBN: (纸本)9798331504557

In this paper, the exergy efficiency of high-pressure heater feedwater in a coal-fired power generation thermal system heated with Therminol VP-1 as the thermal fluid is investigated, and the transient characteristics of the heat exchanger are analyzed after changes in heat transfer oil parameters. The results show that the exergy efficiency of Therminol VP-1 for heating feedwater tends to decrease as the unit load decreases. The exergy efficiency for heating high pressure heater feedwater was 80% to 90%, with a maximum of 90.3%. The time required to reach the new steady state after perturbation of the boundary parameters of the oil-water heat exchanger increased with the load rate, with a minimum of 200 s and a maximum of 500 s in the study range. the new steady state was reached more quickly with increasing load than with decreasing load. © 2024 IEEE.

关键词： Exergy

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Void fraction measurement and calculation model of vertical upward co-current air-water slug flow

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Chinese Journal of Chemical engineering 2022年第11期51卷 178-198页

作者： Teng Wang Miao Gui Jinle Zhao Qincheng Bi Tao Zhang State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049China School of Nuclear Science and Technology Xi’an Jiaotong UniversityXi’an 710049China

The focus of this paper is on the measurement and calculation model of void fraction for the vertical upward co-current air-water slug flow in a circular tube of 15 mm inner diameter. High-speed photography and optical probes were utilized, with water superficial velocity ranging from 0.089 to 0.65 m·s^(-1)and gas superficial velocity ranging from 0.049 to 0.65 m·s^(-1). A new void fraction model based on the local parameters was proposed, disposing the slug flow as a combination of Taylor bubbles and liquid slugs. In the Taylor bubble region, correction factors of liquid film thickness Cδand nose shape CZ*were proposed to calculate aTB. In the liquid slug region, the radial void fraction distribution profiles were obtained to calculate aLS, by employing the image processing technique based on supervised machine learning. Results showed that the void fraction proportion in Taylor bubbles occupied crucial contribution to the overall void fraction. Multiple types of void fraction predictive correlations were assessed using the present data. The performance of the Schmidt model was optimal, while some models for slug flow performed not outstanding. Additionally, a predictive correlation was correlated between the central local void fraction and the cross-sectional averaged void fraction, as a straightforward form of the void fraction calculation model. The predictive correlation showed a good agreement with the present experimental data, as well as the data of Olerni et al., indicating that the new model was effective and applicable under the slug flow conditions.

关键词： Slug flow Gas-liquid flow Void fraction Measurement Optical probe Model

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Data-Driven Surrogate Model for the Dynamic Characteristics of Supercritical Units

Data-Driven Surrogate Model for the Dynamic Characteristics ...

引用

2024 Boao New power System International Forum - power System and New Energy Technology Innovation Forum, NPSIF 2024

作者： Dong, Shuai Zheng, An Jiang, Junyao Gao, Wei Liu, Ming Huaneng Yimin Coal-Power Co. Ltd. Hulunbuir021130 China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China

ISBN: (纸本)9798331504557

Coal-fired power generation units are characterized by large inertia, strong coupling, and high delay, making dynamic characteristic modeling inherently complex and computationally intensive. To address this, this paper utilizes GSE software to explore the dynamic characteristics of supercritical units. Data-driven approaches are then employed to develop surrogate model for these dynamics, comparing neural networks and support vector regression methods in the process. The study indicates that the surrogate model achieves a relative prediction error of less than 1% for live steam temperature, reheater steam outlet temperature, and power output. For live steam pressure and reheater steam outlet pressure, the model maintains a relative error within 10%. © 2024 IEEE.

关键词： Support vector regression

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Numerical simulation on the frosting and heat transfer characteristics of plate-fin heat exchanger considering confinement effect

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Energy Storage and Saving 2022年第3期1卷 136-147页

作者： Xiaoling Yang Xue Liu Xiaojun Dong Yang Meng Yu Hou Tianwei Lai State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an710049China

In refrigerating industry,frost commonly deposits on the confined cold surfaces of heat exchangers,which affects the heat transfer *** the confined flow path of the heat exchanger,the frosting at downstream is affected by the parameters from the *** this study,a numerical model considering the confinement effect has been proposed to predict frosting characteristics in plate-fin heat ***-diffusion equations for humid air and empirical correlations for local frost density are employed in the numerical *** behavior and heat transfer in the confined channel are investigated with different humid air parameters and cold surface *** results indicate that frost thickness in the confined channel is thicker than that in open space under the same inlet *** frost layer is thicker and fluffier along the confined *** addition,the air temperature difference between inlet and outlet of the confined channel enlarges with *** the same average temperature of upper and lower surfaces,the heat and mass transfer of frosting are enhanced with diminishing temperature difference of upper and lower *** such condition,frosting is mainly influenced by the cold surface with the lower temperature.

关键词： Heat exchanger Frosting Confined channel Numerical simulation Heat transfer

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Bubble oscillation and effects of dynamic behaviors on forces and mass transfer in photoelectrochemical water splitting

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Physical Review Fluids 2024年第11期9卷 114305-114305页

作者： Yonglu She Qiang Xu Tengfei Nie Xinyi Luo Mengsha Wang Xingmiao Ye Dengwei Jing State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China

The evolution and coverage of bubbles resulting from gas evolution at the reaction interface significantly impact mass transfer and the flow field within the photoelectrochemical water splitting system, posing a significant obstacle to overcoming the efficiency bottleneck of photoelectrochemical water splitting. In situ bubble observation can be realized via a coupled experimental system combining electrochemical measurements and high-speed imaging. The results indicate that bubble growth behavior correlates with system temperature and operating voltage; that is, the bubbles grow in an oscillating state on the electrode surface at the low operating voltage and high system temperature. Besides, the deviation amplitude of oscillating bubbles increases with system temperature yet decreases with operating voltage. The results indicate that the time coefficient of the growing bubble decreases, while the growth rate and gas evolution efficiency of the bubble increase with the increase of oscillating amplitude in the horizontal direction. The study of dynamic behaviors between the oscillating bubble and the contacted electrode reveals that the bubble oscillation is characterized by the periodic contraction and extension of the triple line. The mass transfer model of concentration boundary layer and the force model of oscillating bubble are constructed based on the interaction between the bubbles and the surrounding flow field. The mass transfer model has considered the microconvection caused by single-phase natural convection, gas-liquid interface expansion, and the oscillation of bubbles. Then through the force balance model, the solutal Marangoni force is found to gradually increase as the contact line extends outward.

关键词： Bubble dynamics Contact line dynamics Marangoni convection Microbubbles multiphase flows

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