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Spontaneous photoelectric field-enhancement effect prompts the low cost hierarchical growth of highly ordered heteronanostructures for solar water splitting

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Nano Research 2016年第6期9卷 1561-1569页

作者： Yankuan Wei Jinzhan Su XiaokangWan Liejin Guo Lionel Vayssieres International Research Center for Renewable Energy State Key Laboratory for Multiphase Flow in Power Engineering School of Energy &Power Engineering Xi'an Jiaotong University Xi'an 710049 China

In this study, a potentially universal new strategy is reported for the large-scale, low-cost fabrication of visible-light-active highly ordered heteronanostructures based on the spontaneous photoelectric-field-enhancement effect inherent in pyramidal morphology. The hierarchical vertically oriented arrayed structures comprise an active molecular co-catalyst at the apex of a visible-light-active large band gap semiconductor for low-cost solar water splitting in a neutral aqueous medium without the use of a sacrificial agent.

关键词： bismuth vanadate co-catalysts photocatalysis solar water splitting oxygen evolution

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Experimental and kinetic study on ignition delay times of methane/hydrogen/oxygen/nitrogen mixtures by shock tube

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Chinese Science Bulletin 2011年第26期56卷 2853-2861页

作者： ZHANG YingJia HUANG ZuoHua WEI LiangJie NIU ShaoDong State Key Laboratory of Multiphase Flow in Power Engineering Xi' an Jiaotong University Xi'an 710049 China

Ignition delay times of methane/hydrogen/oxygen/nitrogen mixtures with hydrogen amount-of-substance fractions ranging from 0–20% were measured in a shock tube *** ambient temperature varied from 1422 to 1877 K and the pressure was maintained at 0.4 MPa behind the reflected shock *** experiments were conducted at an equivalence ratio of *** fuel mixtures were diluted with nitrogen gas so that the nitrogen amount-of-substance fraction was 95%.The experimental ignition delay time of the CH4/H2 mixture decreased as the hydrogen amount-of-substance fraction *** enhancement of ignition by hydrogen addition was weak when the ambient temperature was >1750 K,and strong when the temperature was <1725 *** ignition delay time of 20% H2/80% CH4 was only one-third that of 100% CH4 at 1500 K.A modified model based on GRI-Mech 3.0 was proposed and used to calculate the ignition delay times of test *** calculated results agreed with the experimental ignition delay *** sensitivity analysis showed that HO·+H2 →H·+H2O was the main reaction for the formation of the H· at 1400 *** the hydrogen amount-of-substance fraction increased,chain branching was enhanced through the reaction H·+O2→O·+HO·,and this reduced the ignition delay *** 1800 K,the methyl radical (H3C·) became the key species that influenced the ignition of the CH4/H2/O2/N2 mixtures,and sensitivity coefficients of the chain termination reaction 2H3C·(+M)→C2H6(+M),and chain propagation reaction HO2+H3C·→HO·+CH3O decreased,which reduced the influence of hydrogen addition on the ignition of the CH4/H2 mixtures.

关键词：点火延迟时间混合物动力学激波管氢气实验氮气甲烷

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Supersonic shear layer characteristics of two fluids with a splitter plate

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International Journal of Advanced Nuclear Reactor Design and Technology 2021年 3卷 1-10页

作者： Bai, Yuping Hong, Yibo Zhao, Quanbin Chen, Weixiong Chong, Daotong State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China

Supersonic shear layer development affects mixing between the primary and secondary fluids in a supersonic ejector substantially. The splitter plate plays a key role in shear layer development in the near-trailing-edge region. In this paper, supersonic shear layers with various splitter plate thicknesses are calculated and analyzed. Two types of instability modes are found when various splitter plate thicknesses are used. The shock wave strength and absolute unstable region determine the instability modes. Shock waves can limit instability development but an absolute unstable region promotes instability development. Velocity thickness growth rates are found to be the result of the merging process between two or more adjacent vortices in the transition region. The number of vortices that merge depends on the ratio of the vortex shedding and nature frequencies. The velocity thickness growth rates are larger under the local instability mode than under the global instability mode since three vortices merge under the former mode but two vortices merge under the latter. This study may provide a helpful reference for the design of supersonic ejectors. © 2021 Xi'an Jiaotong University

关键词： Vortex flow

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Experimental and kinetic study on laminar flame speeds of ammonia/syngas/air at a high temperature and elevated pressure

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Frontiers in Energy 2022年第2期16卷 263-276页

作者： Geyuan YIN Chaojun WANG Meng ZHOU Yajie ZHOU Erjiang HU Zuohua HUANG State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049China Key Laboratory for Thermal Science and Power Engineering of the Ministry of Education Department of Thermal EngineeringTsinghua UniversityBeijing 100084China

The laminar flame speeds of ammonia mixed with syngas at a high pressure, temperature, and different syngas ratios were measured. The data obtained were fitted at different pressures, temperatures, syngas ratios, and equivalence ratios. Four kinetic models (the Glarborg model, Shrestha model, Mei model, and Han model) were compared and validated with experimental data. Pathway, sensitivity and radical pool analysis are conducted to find out the deep kinetic insight on ammonia oxidation and NO formation. The pathway analysis shows that H abstraction reactions and NHi combination reactions play important roles in ammonia oxidation. NO formation is closely related to H, OH, the O radical produced, and formation reactions. NO is mainly formed from reaction, HNO+ H= NO+ H2. Furthermore, both ammonia oxidation and NO formation are sensitive to small radical reactions and ammonia related reactions.

关键词： ammonia mixed with syngas laminar flame speed kinetic model sensitivity analysis pathway analysis

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Measurement of laminar burning velocities and analysis of flame stabilities for hydrogen-air-diluent premixed mixtures

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Chinese Science Bulletin 2009年第5期54卷 846-857页

作者： HU ErJiang HUANG ZuoHua HE JiaJia JIN Chun MIAO HaiYan WANG XiBin State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China

The laminar burning velocities and Markstein lengths of the hydrogen-air-diluent mixtures were meas-ured at different equivalence ratios (0.4―1.5), different diluents (N2, CO2 and 15%CO2+85%N2) and di-lution ratios (0, 0.05, 0.10 and 0.15) by using the outwardly expanding flame. The influences of flame stretch rate on the flame propagation characteristics were analyzed. The results show that both the laminar burning velocities and the Markstein lengths of the hydrogen-air-diluent mixtures decrease with the increase of dilution ratio. The decrease in Markstein lengths means that adding diluents into the hydrogen-air mixtures will decrease the diffusional-thermal instability of the flame front. For a specified dilution ratio, the laminar burning velocities give their maximum values at an equivalence ratio of 1.8. The Markstein lengths increase with the increase of the equivalence ratio monotonously regardless of the diluents. The study shows that CO2 as the diluent has a greater impact on the laminar flame speed and the flame front stability than N2 as the diluent.

关键词：氢气空气混合火焰特性燃烧速度稳定性

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Modeling and prediction of ultrasonic attenuations in liquid-solid dispersions containing mixed particles with Monte Carlo method

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Particuology 2019年第2期17卷 84-91页

作者： Jianfei Gu Fengxian Fan Yunsi Li Huinan Yang Mingxu Su Xiaoshu Cai Institute of Particle and Two-Phase Flow Measurement/Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering University of Shanghai for Science and Technology Shanghai 200093 China

We develop a theoretical model for predicting the ultrasonic attenuation in the liquid-solid system containing mixed particles. The ultrasonic attenuation coefficient is obtained by counting the number of phonons that reach the receiver. Using the Monte Carlo method (MCM), numerical simulations were performed to predict the ultrasonic attenuations with not only a single particle type but also monodisperse and polydisperse mixed particles. The simulation results for the systems with a single particle type were compared with various standard models. The results show that they agree well at relatively low particle volume concentrations (within 10%). For systems with mixed particles, the particle volume concentrati on was found to in crease to around 10%, and the variation of the ultrasonic attenuation agai nst the mixing ratio yields a nonlinear trend. Moreover, the ultrasonic attenuation is significantly affected by particle properties. The numerical results also show that both the particle type and particle size distribution should be carefully taken into account in the dispersions with polydisperse mixed particles, where the MCM can give a more direct description of the physics of sound propagation compared with the conventional models.

关键词： Ultrasound Ultrasonic attenuation Monte Carlo method Particle size measurement

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Evaluating the chemical kinetics of aluminium/alumina/water reactions using molecular dynamics

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Computational Materials Science 2025年 257卷

作者： Zhao, Hao Zhang, Yingjia Liu, Yuncong Huang, Zuohua State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University No.28 Xianning West Road Shaanxi Xi'an710049 China

Strength of aluminium in generating heat and hydrogen through water reaction highlight its potential as a green hydrogen carrier, but the formation of a passive oxide layer (alumina) inhibits further reactions thus hydrogen yield. This study employs reactive molecular dynamics (MD) simulations with the ReaxFF force field to investigate interactions between water and alumina-coated aluminium surfaces at temperatures ranging from 1000 K to 2500 K. Analysis of diffusion-driven reaction kinetics shows that hydrogen generation is primarily controlled by hydrogen atom diffusion within the aluminium bulk. Higher temperatures significantly accelerate both diffusion and reaction rates, shifting the mechanism from diffusion-limited to chemically controlled. Atomic-level reaction pathway analysis, using an in-house atom status tracing code, reveals the dynamic evolution of aluminium atom states. The results emphasize the roles of hydrogen and oxygen diffusion and indicate that O–H bond cleavage mainly proceeds through internal atomic diffusion. These findings offer detailed atomic-scale insight into the aluminium-water reaction, capturing both oxidizer diffusion and thermal effects. The study highlights the importance of thermal activation in enhancing reaction efficiency and safety, reinforcing aluminium's potential for green hydrogen production in carbon–neutral energy systems. © 2025 Elsevier B.V.

关键词： Rate constants

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Distribution of void fraction for gas-liquid slug flow in aninclined pipe

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Nuclear Science and Techniques 2001年第2期12卷 143-148页

作者： XIA Guo-Dong1, ZHOU Fang-De2, HU Ming-Sheng2 (1 College of Environmental and Energy engineering, Beijing Polytechnic University, Beijing 100022 2 State key laboratory of multiphase flow in power engineering, Xi’an Jiaotong University, xi’an 710049) College of Environmental and Energy Engineering Beijing Polytechnic University State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University

In order to investigate the effect of inclination angle on the spatial distribution of phases, experiments on gas-liquid two-phase slug flow in an inclined pipe were carried out by using the optical probe and an EKTAPRO 1000 high speed motion analyzer. It has been demonstrated that the inclination angle and the mixture velocity are important parameters to influence the distribution of void fraction for upward slug flow in the inclined pipe. At high mixture velocity, the gas phase profile is axial symmetry in the cross-section of the pipe. This is similar to that for vertical slug flow. In contrast, most of the gas phase is located near the upper pipe wall at low mixture velocity. By measuring the axial variation of void fraction along the liquid slug, it can be concluded that there is a high void fraction wake region with length of 3～4D in the front of liquid slug. In the fully developed zone of liquid slug, the peak value of the void fraction is near the upper wall.

关键词：气-液二相流斜管相分布

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Impact of bimetallic synergies on Mo-doping NiFeOOH:Insights into enhanced OER activity and reconstructed electronic structure

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Frontiers in Energy 2024年第6期18卷 850-862页

作者： Jingkuo Qu Yuchen Dong Tuo Zhang Chang Zhao Liting Wei Xiangjiu Guan International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong UniversityXi’an 710049China

NiFe(oxy)hydroxide(NiFeOOH)is recognized as a highly active non-precious metal catalyst in alkaline water electrolysis due to its exceptional catalytic *** this work,high valence molybdenum(Mo)is introduced to improve the electronic structure and enhance the electrical conductivity of NiFeOOH for oxygen evolution reaction(OER).The introduction of Mo results in a Mo-doped NiFeOOH catalyst with a significantly reduced overpotential of 205 mV at 10 mA/cm^(2)and a Tafel slope of 31.7 mV/dec,enabling stable operation for up to 170 *** empirical experiment and theory simulations are employed to gain insight into the 3d-electron interactions between molybdenum and nickel(Ni),iron(Fe)in Mo-doped *** results indicate that Mo-doping enhances the valence states of Ni and Fe,leading to a shift in the d-band center of the bimetallic active *** modification affects the transformation of Mo-doped NiFeOOH into theγ-NiFeOOH active *** potent combination lends credence to its potential suitability and utility in OER applications.

关键词： Mo doping NiFe(oxy)hydroxide(NiFeOOH) bimetallic synergies oxygen evolution reaction(OER) electronic structure

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Measurement of laminar burning velocities of iso-butanol-air mixtures

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Chinese Science Bulletin 2010年第19期55卷 2046-2056页

作者： FENG PengFei GU XiaoLei HUANG ZuoHua State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China

The laminar burning velocity of iso-butanol-air mixtures was measured under different initial pressures,initial temperatures and equivalence ratios using high-speed schlieren photography and outwardly propagation flame in a constant volume combustion *** on the analysis of stretched flame propagation speed and stretch rate,the laminar burning velocities and Markstein lengths of iso-butanol-air flames are *** accordance,with photos of flame,an analysis of flame stability and the influencing factors is carried *** results show that the laminar burning velocity is decreased with the increase of initial pressure and is increased with the increase of initial *** maximum value of laminar burning velocity is presented at the equivalence ratio of *** Markstein length is decreased with the increase of equivalence *** specified equivalence ratio,the Markstein length is decreased with the increase of initial temperature and initial ***,the flame instability is increased with the increase of equivalence ratio,initial temperature and initial pressure.

关键词：层流燃烧速度空气混合物速度测定异丁醇火焰传播速度初始压力初始温度当量比

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