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ASME 2024 power Conference, power 2024

作者： Chen, Chen Liu, Ming Wang, Chaoyang Zhao, Yongliang Yan, Hui Yan, Junjie State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an China

ISBN: (纸本)9780791888186

With the increasing penetration of renewable power, flexible power sources are urgently required by the power grid to balance the supply and demand sides. Therefore, the operational flexibility of subcritical coal-fired power plants should be further enhanced. In this study, dynamic models of a reference 330MW subcritical coal-fired power plant were developed and validated. The load ramp performances of the reference plant were simulated. The maximum ramp rates during loading down processes were 2%Pe/min and 1.5%Pe/min in 75% -50% and 50% -40% load cycling ranges, respectively, and the maximum ramp rate during loading up processes is 1.5%Pe/min. That the live steam and reheat steam temperatures exceeding their thresholds limits for the load ramp rates. The subcritical power unit has a steam drum, serving as a substance and energy storage device, and allows partial decoupling of feedwater flow and coal flow. Consequently, an enhanced steam temperature control strategy, facilitated by adjusting the feedwater flow rate during the load ramp processes, was proposed. The feedwater flow rate is appropriately regulated during load cycling dynamic processes to assist the control of live steam and reheat steam temperatures. The models to obtain the live steam and reheat steam temperature variations influenced by the feedwater flow rates are developed, and implemented in the control strategy. Then, simulations on the reference power plant with the enhanced control strategy were conducted, and the temperature overshoots have been effectively suppressed. As a result, the load ramp rate is increased. For example, in the load cycling range of 75%-40%, the overall unit ramp rate is increased by 1%Pe/min, achieving an enhancement in the operational flexibility of subcritical units. Copyright © 2024 by ASME.

关键词： Coal

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STRESS ANALYSIS AND LIFE ASSESSMENT OF THE STEAM TURBINE ROTOR DURING PEAK SHAVING TRANSIENT PROCESSES

STRESS ANALYSIS AND LIFE ASSESSMENT OF THE STEAM TURBINE ROT...

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ASME 2024 power Conference, power 2024

作者： Fan, Mengyang Zhao, Yongliang Liu, Ming Wang, Chaoyang Wang, Zhu Yan, Junjie State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an China

ISBN: (纸本)9780791888186

To achieve the net-zero emissions targets, the global share of renewable energy is rapidly increasing. The high penetration of intermittent and variable renewable power necessitates that coal-fired power plants enhance their operational flexibility for peak shaving and frequency regulation. Frequent and rapid start-ups, shutdowns, and peak shaving processes pose significant safety challenges to the steam turbine rotors. This paper investigates the impact of flexible operation on rotor stress. Firstly, an online monitoring model was developed and verified using a finite element model of a steam turbine high-medium pressure rotor. Secondly, the online calculation model was integrated with a dynamic coal-fired unit model developed using the JTopmeret software on the GSE platform, a well-established dynamic simulation tool for nuclear and fossil fuel power plants. Finally, a rotor low-cycle fatigue life assessment model was developed, and the von Mises stress and fatigue life loss under various load variation rates and ranges were determined. As the load variation rate increases, the life loss increases significantly, with maximum von Mises stress amplitudes of 5.2, 6.5 and 7.8 MPa at 1%, 2% and 3% Pe min−1 load variation rates, respectively. Conversely, as the load variation range increases, the life loss decreases substantially, with maximum von Mises stress amplitudes of 9.2 and 5.0 MPa during load variation processes of 50%-75% and 75%-100% THA, respectively. This study provides detailed guidance for optimizing the safe operation and control strategies of coal-fired power plants. Copyright © 2024 by ASME.

关键词： Steam turbines

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Formic acid dehydrogenation reaction on high-performance Pd_(x)Au_(1−x) alloy nanoparticles prepared by the eco-friendly slow synthesis methodology

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Frontiers in Energy 2023年第6期17卷 751-762页

作者： Yibo GAO Erjiang HU Bo HUANG Zuohua HUANG State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049China Institute of Chemical Engineering and Technology Xi’an Jiaotong UniversityXi’an 712000China

Dehydrogenation of formic acid (FA) is considered to be an effective solution for efficient storage and transport of hydrogen. For decades, highly effective catalysts for this purpose have been widely investigated, but numerous challenges remain. Herein, the Pd_(x)Au_(1−x) (x = 0, 0.2, 0.4, 0.5, 0.6, 0.8, 1) alloys over the whole composition range were successfully prepared and used to catalyze FA hydrogen production efficiently near room temperature. Small PdAu nanoparticles (5–10 nm) were well-dispersed and supported on the activated carbon to form PdAu solid solution alloys via the eco-friendly slow synthesis methodology. The physicochemical properties of the PdAu alloys were comprehensively studied by utilizing various measurement methods, such as X-ray diffraction (XRD), N2 adsorption–desorption, high angle annular dark field-scanning transmission electron microscope (HAADF-STEM), X-ray photoelectrons spectroscopy (XPS). Notably, owing to the strong metal-support interaction (SMSI) and electron transfer between active metal Au and Pd, the Pd0.5Au0.5 obtained exhibits a turnover frequency (TOF) value of up to 1648 h−1 (313 K, nPd+Au/nFA = 0.01, nHCOOH/nHCOONa = 1:3) with a high activity, selectivity, and reusability in the FA dehydrogenation.

关键词： FA dehydrogenation face-centred cubic structures PdAu solid solution alloy nanoparticles slow synthesis methodology SMSI effect

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Effect of Particle Orientation on Heat Transfer in Arrays of Prolate Particles

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Computer Modeling in engineering & Sciences 2023年第8期136卷 1509-1526页

作者： Romana Basit Xinyang Li Zheqing Huang Qiang Zhou School of Chemical Engineering and Technology Xi’an Jiaotong UniversityXi’anChina State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’anChina

Direct Numerical Simulations have been carried out to study the forced convection heat transfer of flow through fixed prolate particles for a variety of aspect ratios ar={5/4,5/3,5/1}with Reynolds number(Re)up to *** variations of the solid volume fraction c={0.1,0.2,0.3}with four Hermans orientation factors S={−0.5,0,0.5,1}are *** has been found that changes in S cause prominent variations in the Nusselt *** general,Nusselt number increases with the decrease of *** all three aspect ratios,the Nusselt number remains a linear function of S at different c and ***,it is concluded that,for heat transfer from prolate muti-particle system,the effects of orientations cannot be ignored.A new correlation for Nusselt number has been developed for arrays of prolate particles using the simulation data as a function of Re,c,S and ar.

关键词： Direct Numerical Simulation heat transfer lattice Boltzmann method particle orientations prolate particles

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Performance and Sizes of sCO_(2)Multistage Axial Compressors at Various power Capacities

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Journal of Thermal Science 2025年第2期34卷 352-373页

作者： WANG Tianze XU Jinliang ZHENG Haonan QI Jianhui Beijing Key Laboratory of Multiphase Flow and Heat Transfer for Low Grade Energy Utilization North China Electric Power UniversityBeijing100026China Key Laboratory of Power Station Energy Transfer Conversion and System(North China Electric Power University) Ministry of EducationBeijing102206China School of Energy and Power Engineering Shandong UniversityJi’nan250061China

The supercritical carbon dioxide(sCO_(2))cycle can be powered by traditional as well as clean *** help users obtain more accurate results than the literatures with pre-set compressor efficiency,we proposed a complete model to establish a link between the performance,sizes of compressors and parameters such as power W_(C),inlet temperature T_(in),inlet pressure P_(in)and pressure ratioε.Characteristic sizes of compressors l_(c),profile loss Y_(p)and clearance loss Ycl are all proportional to powers of W_(C)with powers of 0.5,-0.075 and-0.5 to 0 respectively;the scaling laws are constant in the range of capacities from 20 MW to 200 *** compressor isentropic efficiencyη_(tt)grows as the W_(C)increases,and the curves become *** efficiency improves over the full power range when the speed is changed from standard speed to the optimal speed;theη_(tt)curves turn soft as the n *** the P_(in)and T_(in)approach the critical point,theη_(tt)*** efficiency follows a parabolic curve as theεincreases,this parabolic distribution results from the tradeoff between the change in losses and the pressure distribution of ***η_(tt)versus P_(in),T_(in)andεrelations are similar at various capacities because of insignificant changes in the distribution of *** efficiency maps facilitate the estimation of system performance,while scaling law for irreversible losses and characteristic lengths,along with constant criterion analyses,aid in comprehending the characteristics of compressors across various capacities.

关键词： sCO_(2)cycle compressor efficiency irreversible losses scaling laws

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Polarized imaging dynamic light scattering for simultaneous measurement of nanoparticle size and morphology

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Particuology 2024年第2期85卷 213-223页

作者： Bingyao Wang Tianyi Cai Xiaoshu Cai Wu Zhou Zeqi Liu Schoolof Energy and Power Engineering University of Shanghai for Science and TechnologyShanghai200093China Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering Shanghai200093China Jiaxing MeaParTech Instrument Technology Co. LtdZhejiang314000China

The performance of nanoparticles is often affected by particle size and ***,electron microscopy or atomic force microscopy is typically utilized to determine the size and morphology of ***,there are issues such as difficult sample preparation,long processing times,and challenges in quantitative ***,it is of great significance to develop a fast,accu-rate,and statistical method to measure the size and morphology of *** this study,a new method,called polarized imaging dynamic light scattering(PIDLS),is *** nanoparticles are irradiated with a vertical linearly polarized laser beam,and a polarization camera collected the dynamic light scattering images of particles at four different polarization directions(0°,45°,90°,and 135°)at a scattering angle of 90°.The average particle size and distribution are obtained using the imaging dy-namic light scattering method at 0°polarization direction,and the morphology of the particles is ob-tained based on the depolarization patterns of the scattered *** optical sphericityΦis defined based on the degree of linear polarization(DoLP).It is also implemented for the quantitative evaluation of the sphericity of the nanoparticles,including spherical,octahedral,nanoplate,nanorod,and linear *** with the Poincarésphere parameterψ,the morphology of the nanoparticles can be roughly *** addition,PIDLS enables the measurement of particle size and morphology distributions simultaneously for evaluating the uniformity of *** effectiveness of PIDLS is verified by the measurement of five kinds of industrial titanium dioxide as well.

关键词： Imaging dynamic light scattering Polarized light scattering Non-spherical nanoparticles Morphology Online measurement

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Electrospinning engineering of gas electrodes for high-performance lithium-gas batteries

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Carbon Energy 2024年第10期6卷 353-398页

作者： Jingzhao Wang Xin Chen Jianan Wang Xiangming Cui Ze Wang Guangpeng Zhang Wei Lyu Maxim Shkunov S.Ravi P.Silva Yaozu Liao Kai Yang Wei Yan State Key Laboratory of Multiphase Flow in Power Engineering Department of Environmental Science and EngineeringSchool of Energy and Power EngineeringXi'an Jiaotong UniversityXi'anChina Advanced Technology Institute University of SurreyGuildfordSurreyUK State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and EngineeringDonghua UniversityShanghaiChina

Lithium-gas batteries(LGBs)have garnered significant attention due to their impressive high-energy densities and unique gas conversion ***,the practical application of LGBs faces substantial challenges,including sluggish gas conversion kinetics inducing in low-rate performance and high overpotential,along with limited electrochemical reversibility leading to poor cycle *** imperative task is to develop gas electrodes with remarkable catalytic activity,abundant active sites,and exceptional electrochemical ***,a versatile and well-established technique for fabricating fibrous nanomaterials,has been extensively explored in LGB *** this work,we emphasize the critical structure-property for ideal gas electrodes and summarize the advancement of employing electrospun nanofibers(NFs)for performance enhancement in *** elucidating the fundamental principles of LGBs and the electrospinning technique,we focus on the systematic design of electrospun NF-based gas electrodes regarding optimal structural fabrication,catalyst handling and activation,and catalytic site optimization,as well as considerations for large-scale *** demonstrated principles and regulations for electrode design are expected to inspire broad applications in catalyst-based energy applications.

关键词： carbon nanofibers electrocatalyst electrospinning gas electrodes metal-gas batteries

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Particle convective heat transfer near the wall in a supercritical water fluidized bed by single particle model coupled with CFD-DEM

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Particuology 2023年第2期73卷 47-58页

作者： Tianning Zhang Zhen Wan Youjun Lu State Key Laboratory of Multiphase Flow in Power Engineering(SKLMFPE) Xi'an Jiaotong UniversityXi'an710049ShaanxiChina Xi'an Electronic Engineering Research Institute Xi'an710100ShaanxiChina

Supercritical water fluidized bed(SCWFB)is a promising reactor to gasify biomass or *** optimization design is closely related to wall-to-bed heat transfer,where particle convective heat transfer plays an important *** paper evaluates the particle convective heat transfer coefficient(h_(pc))at the wall in SCWFB using the single particle *** critical parameters in the single particle model which is difficult to get experimentally are obtained by the computational fluid dynamics-discrete element method(CFD-DEM).The contact statistics related to particle-to-wall heat transfer,such as contact number and contact distance,are also *** results show that particle residence time(τ),as the key parameter to evaluate h_(pc),is found to decrease with rising velocity,while increase with larger thermal boundary layer thickness.τfollows a gamma function initially adopted in the gas-solid fluidized bed,making it possible to evaluate h_(pc) in SCWFB by a simplified single particle *** theoretical predicted h_(pc) tends to increase with rising thermal gradient thickness at a lower velocity(1.5 U_(mf)),while first decreases and then increases at higher velocity(1.75 and 2 U_(mf)).h_(pc) occupies 30%-57%of the overall wall-to-bed heat transfer coefficient for a particle diameter of 0.25 *** results are helpful to predict the overall wall-to-bed heat transfer coefficient in SCWFB combined with a reasonable fluid convective heat transfer model from a theoretical perspective.

关键词： Supercritical water Fluidized bed Particle residence time Discrete element method Single particle model

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Review of spatial scale dispersion models (ATDMs) to simulate environmental dispersion and deposition of radionuclides and the overview of GIS coupling with dispersion models

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International Journal of Advanced Nuclear Reactor Design and Technology 2024年第4期6卷 256-280页

作者： Muhammad, Hussaini Xuan, Wang Wang, Mingjun Su, Guanghui School of Nuclear Science and Technology Shanxi Key Laboratory of Advanced Nuclear Energy and Technology State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China Abuja Nigeria

Estimation of the radiological consequences including the calculation of radiation doses to the exposed population requires numerical evaluation of atmospheric radioactive releases from nuclear facilities under accidental scenarios for implementation of adequate protective and other response actions to prevent or minimize severe deterministic effects and reduce the probability of occurrence of stochastic effects. This paper reviews various state-of-the-art spatial scale atmospheric dispersion models, known as the ATDMs, designed to evaluate atmospheric transport, dispersion, and depositions of radionuclide emissions from release sources. The ATDMs (atmospheric transport, dispersion, and deposition models) reviewed in this paper are FLEXPART, CALPUFF, LADAS, RASCAL, RIMPUFF, and HotSpot. These ATDMs are increasingly applied to perform probabilistic radiological risk assessment, which is one of the IAEA safety requirements for site evaluation of new NPP, and the calculated doses can be used to establish EPZs, an underlying basis of emergency preparedness. The numerical approaches, modeling methodology, advantages, limitations, scope of applications, and research investigations performed using these models in radiological and other environmental impact assessments within their scope of applications are presented. GIS has been widely recognized as a technique applied to aid the modeling of pollutant dispersion and visualization of model outputs in a spatial context, among other benefits. In nuclear accident consequence evaluation, spatial data provides key information such as accident location, range of radiological contamination, population density, etc, which are very important. This demonstrates the high significance of GIS-ATDMs coupling. Therefore, an overview of the coupling of dispersion models with GIS is also highlighted. © 2025 Xi'an Jiaotong University

关键词： Risk assessment

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Modulating redox transition kinetics by anion regulation in Ni-Fe-X(X=O,S,Se,N,and P)electrocatalyst for efficient water oxidation

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Nano Research 2024年第6期17卷 4720-4728页

作者： Liting Wei Kaini Zhang Rui Zhao Lei Zhang Yan Zhang Suyi Yang Jinzhan Su International Research Center for Renewable Energy&State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049China Department of Applied Chemistry Yuncheng UniversityYuncheng 044000China

NiFe-based electrocatalysts will experience dynamical surface reconstruction during oxygen evolution reaction(OER)process,and the derived metal(oxy)hydroxide hybrids on the surface have been considered as the actual active species for *** efforts have been dedicated to understanding the surface reconstruction,but there is rare research on recognizing the origin of improved performance derived from anion species of ***,the OER electrocatalytic characteristics were tuned with different anions in NiFe-based catalyst,using NiFe-based oxides/nitride/sulfide/selenides/phosphides(NiFeX,X=O,N,S,Se,and P)as the model *** combination of X-ray photoelectronic spectroscopy,electrochemical tests,operando spectroscopic characterizations,and density functional theory(DFT)calculations,reveals that anion with lower electronegativity in NiFe-based catalyst leads to higher conductivity and delayed valence transition of Ni sites,as well as optimized adsorption behavior towards oxygen intermediates,contributing to enhanced OER ***,NiFeP electrocatalyst demonstrates an ultralow overpotential of 265 mV at 20 mA·cm−2 for OER,as well as long-term *** work not only offers further insights into the effect of anionic electronegativity on the intrinsic OER electrocatalytic properties of NiFe-based electrocatalyst but also provides guide to design efficient non-noble metal-based electrocatalysts for water oxidation.

关键词： oxygen evolution reaction(OER) anion species electronegativity valence transition

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