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Metal-organic polyhedra as dynamic cross-linker for recyclable mixed matrix membranes with promising dimension stability

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Science China Chemistry 2025年第2期68卷 705-713页

作者： Linjie Lan Mingxin Zhang Haiyan Xiao Wei Liu-Fu Yuyan Lai Jiadong Chen Jia-Fu Yin Panchao Yin State Key Laboratory of Luminescent Materials and Devices&South China Advanced Institute for Soft Matter Science and Technology Guangdong Basic Research Center of Excellence for Energy and Information Polymer MaterialsSouth China University of TechnologyGuangzhou 510641China State Key Laboratory of Marine Resource Utilization in South China Sea Hainan Provincial Key Lab of Fine ChemistrySchool of Chemical Engineering and TechnologyHainan UniversityHaikou 570228China

Mixed matrix membranes(MMMs)are designed by incorporating microporous inorganic fillers into polymer matrix for the integration of inorganics’excellent gas separation performance with polymers’promising ***,due to the complex interphase interaction,the prevention of long-term aging is still challenging and the poor processability/recyclability of MMMs hinders their extensive ***,a coordination assembly protocol is developed for the fabrication of MMMs with both excellent processability/recyclability upon thermal annealing and promising dimension stability even under high gas *** bearing isophthalic acid(IPA)as side chains are applied to coordinate with Cu^(2+)and the assembled 2.5 nm microporous metal-organic polyhedra(MOP),{Cu_(24)IPA_(24)},serves as multi-functional cross-linkers for the polymer network *** MOPs’well-defined microporosity grants MMMs the capability for O_(2)/N_(2) separation while their activated dynamics at high temperatures(>120℃)endows polymer networks with excellent *** contrast to conventional supramolecular units,the MOPs possess unique logarithmic ligand-exchange kinetics and they show nearly frozen bonding dynamics at room temperature,ensuring promising dimensional stability to overcome the long-term aging and high gas pressure *** work not only provides fundamental understanding of the unique relaxation dynamics of complex systems with intertwined dynamics of supramolecular bonds and polymer chains,but also paves new avenues for the fabrication of robust and recyclable MMMs and elastomers.

关键词： dynamic bonding metal-organic polyhedra mixed matrix membrane polymer recycling gas separation

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Understanding interfacial engineering of surface functionalized boron nitride nanosheets within thermal interface materials

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Science China Materials 2025年第4期68卷 1300-1302页

作者： Gaojie Han Yuezhan Fengg Changyu Shen State Key Laboratory of Structural Analysis Optimization and CAE Software for Industrial EquipmentNational Engineering Research Center for Advanced Polymer Processing TechnologyZhengzhou UniversityZhengzhou 450002China

The continuous miniaturization and high-power development of electronic devices have given rise to severe interface thermal issues,which urgently demand highly thermally conductive thermal interface materials(TIMs)to ... 详细信息

关键词： interfacial engineering heat accumulation interface thermal issueswhich thermal interface materials surface functionalized boron nitride nanosheets electronic devices thermal conductivity

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Water enhances photocatalytic activity for toluene selective oxidation in acetic acid solution

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Nano Research 2025年第3期18卷 223-233页

作者： Sheng Tian Jinxin Li Binghao Wang Xiong Wang Xingsheng Hu Huijuan Wang Lang Chen Shuang-Feng Yin Advanced Catalytic Engineering Research Center of the Ministry of Education State Key Laboratory of Chemo/Biosensing and ChemometricsCollege of Chemistry and Chemical EngineeringHunan UniversityChangsha 410082China College of Chemistry and Chemical Engineering Central South University of Forestry and TechnologyChangsha 410004China

Photocatalytic oxidation of hydrocarbons to value-added oxygen-containing compounds is a green and sustainable ***,the efficient activation of C(sp^(3))-H bonds under mild conditions remains a significant *** this study,we prepared BiOBr/Bi_(2)MoO_(6)Z-scheme heterostructure for photocatalytic selective oxidation of toluene to benzaldehyde utilizing acetic acid as solvent.A small amount of water as an additive established an acidic environment to facilitate the formation of highly reactive hydroxyl radicals(·OH)through the O_(2)→·O_(2)^(−)→H_(2)O_(2)→·OH ***·OH together with photogenerated holes acted as reactive species dissociate C(sp^(3))-H bonds,which is regarded as the rate-determining step for this reaction,boosting photocatalytic *** to the reaction system without water,the conversion of toluene increased from 23.6%to 39.0%,reaching a toluene conversion rate of 6110μmol·g^(-1)·h^(-1).Additionally,there is a slight improvement in the selectivity of benzaldehyde.

关键词： photocatalytic oxidation of toluene H_(2)O acidic chemical environment hydroxyl radicals BiOBr/Bi_(2)MoO_(6)

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Defects response to precoated adhesive in Al/steel friction stir welded joint

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Journal of Manufacturing Processes 2025年 141卷 1109-1118页

作者： Huang, Weiben Ding, Zhijie Li, Peng Zhao, Peng Zhou, Dianwu Huang, Yongxian Meng, Xiangchen Li, Yongbing Ma, Yunwu Dong, Honggang School of Materials Science and Engineering Dalian University of Technology Dalian116024 China State Key Laboratory of Advanced Design and Manufacturing Technology for Vehicle Hunan University Changsha410082 China State Key Laboratory of Precision Welding & Joining of Materials and Structures Harbin Institute of Technology Harbin150001 China State Key Laboratory of Mechanical System and Vibration Shanghai Jiao Tong University Shanghai200240 China

Friction stir welding (FSW) has been applied for welding dissimilar materials in advanced manufacturing industries such as shipbuilding, automotive and aerospace. For the broad popularization of adhesive in FSW, the innovative coupling method of friction stir welding-adhesive bonding (FSW-AB) technology was designed to join 5A06 aluminum alloy to 304 stainless steel. The joints were fabricated using a single-component structural adhesive applied manually in the pre-lap zone. The joints were then cured by the heat generated from FSW. Macrostructure, defect generation and tensile shear performances of the joints obtained using three different rotation speeds and different adhesive thickness were studied. The adhesive prevented direct plate contact, but the FSW-AB joint showed more flash. Adhesive expansion occurred on the advancing side due to structural asymmetry and uneven heat dissipation. Compared to conventional FSW, the joints produced by FSW-AB exhibited significantly reduced hook defects in the pin-affected zone, a smoother distribution of hardness across the weld cross-section, and notably elevated hardness on the retreating side of the base metal outside the shoulder. It is attributed to the difference in the degree of crystallization between the two caused by the difference in heat dissipation rate. The ultimate tensile shear load of the FSW-AB joint reached 93.3 % of the conventional FSW joint at 1200 rpm stirring speed and 0.25 mm adhesive thickness. Furthermore, the fracture modes of FSW-AB joints were mainly normal fracture and shear fracture. © 2025 The Society of Manufacturing Engineers

关键词： Vickers hardness

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Efficient and Stable Photoassisted Lithium‑Ion Battery Enabled by Photocathode with Synergistically Boosted Carriers Dynamics

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Nano-Micro Letters 2025年第3期17卷 440-454页

作者： Zelin Ma Shiyao Wang Zhuangzhuang Ma Juan Li Luomeng Zhao Zhihuan Li Shiyuan Wang Yazhou Shuang Jiulong Wang Fang Wang Weiwei Xia Jie Jian Yibo He Junjie Wang Pengfei Guo Hongqiang Wang State Key Laboratory of Solidification Processing Center for Nano Energy MaterialsSchool of Materials Science and EngineeringNorthwestern Polytechnical University and Shaanxi Joint Laboratory of Graphene(NPU)Xi’an 710072People’s Republic of China State Key Laboratory of Solidification Processing School of Materials Science and Engineering DepartmentNorthwestern Polytechnical UniversityXi’an 710072People’s Republic of China State Key Laboratory of Solidification Processing Center of Advanced Lubrication and Seal MaterialsSchool of Materials Science and EngineeringNorthwestern Polytechnical UniversityXi’an 710072People’s Republic of China Research and Development Institute of Northwestern Polytechnical University in Shenzhen Shenzhen 518063People’s Republic of China Key Laboratory of Applied Surface and Colloid Chemistry Shaanxi Key Laboratory for Advanced Energy DevicesShaanxi Engineering Lab for Advanced Energy TechnologySchool of Materials Science and EngineeringNational Ministry of EducationShaanxi Normal UniversityXi’an 710119People’s Republic of China

Efficient and stable photocathodes with versatility are of significance in photoassisted lithium-ion batteries(PLIBs),while there is always a request on fast carrier transport in electrochemical active *** work proposes a general approach of creating bulk heterojunction to boost the carrier mobility of photocathodes by simply laser assisted embedding of plasmonic *** employed in PLIBs,it was found effective for synchronously enhanced photocharge separation and transport in light charging ***,experimental photon spectroscopy,finite difference time domain method simulation and theoretical analyses demonstrate that the improved carrier dynamics are driven by the plasmonic-induced hot electron injection from metal to TiO_(2),as well as the enhanced conductivity in TiO2 matrix due to the formation of oxygen vacancies after Schottky *** from these merits,several benchmark values in performance of TiO2-based photocathode applied in PLIBs are set,including the capacity of 276 mAh g^(−1) at 0.2 A g^(−1) under illumination,photoconversion efficiency of 1.276%at 3 A g^(−1),less capacity and Columbic efficiency loss even through 200 *** results exemplify the potential of the bulk heterojunction strategy in developing highly efficient and stable photoassisted energy storage systems.

关键词： Photoassisted lithium-ion batteries Bulk heterojunction Carrier dynamics TiO2 nanofiber Plasmonic metal nanocrystals

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Promoting effect of d-band center and in-situ precipitation strategy on sulfur evolution reaction

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Journal of Energy Chemistry 2025年第5期104卷 740-748页

作者： Jun Pu Yun Tan Jiasen Yin Zihan Shen Shoujie Liu Kai Zhang Lei Zhou Yagang Yao Key Laboratory of Functional Molecular Solids Ministry of Education Anhui Provincial Engineering Laboratory for New-Energy Vehicle Battery Energy-Storage Materials College of Chemistry and Materials Science Anhui Normal University National Laboratory of Solid State Microstructures College of Engineering and Applied Sciences Jiangsu Key Laboratory of Artificial Functional Materials Collaborative Innovation Center of Advanced Microstructures Nanjing University State Key Laboratory of Multiphase Complex Systems Institute of Process Engineering Chinese Academy of Sciences School of Materials Science and Engineering Anhui University School of Energy and Power Engineering Jiangsu University Department of Electrical Engineering Eindhoven University of Technology

The slow conversion of polyphase in lithium-sulfur （Li-S） batteries not only intensifies the shuttle effect of lithium polysulfides （LiPSs）,but also causes the continuous accumulation of inactive sulfur species,resulting in rapid capacity attenuation and sluggish dynamic ***,the promoting effect of atomic interface stress on sulfur reaction was investigated via CoFe-CoFe2O4heterogeneous nanosheets with a cavity *** strain force induced by the in-situ precipitation of Co Fe bimetallic alloy in oxide matrix increased the d-band center,which was conducive to the interaction between catalyst and Li *** sulfur cathode based on this two-dimensional （2D） nanosheet design showed an extremely high capacity of 751 mAh g-1at 4 *** with a sulfur loading of 5.55 mg cm-2,its area capacity was still as high as 7.15 mAh ***,the enhanced stability greatly improved the practical potential of Li-S batteries.

关键词： 2D nanosheets D-band center In-situ precipitation Li-S batteries Strain effect

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Effect of electrochemical hydrogen charging on the microstructure and mechanical behavior of a duplex structured Mg-8wt.%Li alloy

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Journal of Magnesium and Alloys 2025年第2期13卷 668-680页

作者： Shuo Wang Daokui Xu Baojie Wang Dongliang Wang Zhiqiang Zhang Li Liu Jie Chen Key Lab of Electromagnetic Processing of Materials Ministry of EducationNortheastern UniversityShenyang110819China Key Laboratory of Nuclear Materials and Safety Assessment Institute of Metal ResearchChinese Academy of SciencesShenyang110016China Engineering Research Center of Advanced Materials Preparing Technology Ministry of EducationNortheastern UniversityShenyang110819China Binzhou Institute of Technology BinzhouShandong Province256606China Shandong Key Laboratory of Advanced Aluminium Materials and Technology BinzhouShandong Province256606China School of Environmental and Chemical Engineering Shenyang Ligong UniversityShenyang110159China Spallation Neutron Source Science Center Dongguan523803China

In this work,through performing microstructural characterization,tensile testing and failure analysis,the influence of electrochemical hydrogen charging on the microstructure and mechanical behavior of an as-cast Mg-8wt.%Li alloy was *** revealed that after being hydrogen charged at 50 mA/cm2 for respectively 3 h,6 h and 18 h in 0.1 M NaCl solution,obvious HID occurred and the damage degree was gradually increased with the hydrogen charging *** the sample being hydrogen charged for 3 h,micro pores with the diameter ranging from 10~30µm were formed and preferentially present inα-Mg ***,micro cracks with the length ranging from 10~50µm mainly initiated inα-Mg phase,atα-Mg/β-Li interfaces and the peripheries of *** the increase of hydrogen charging time,the numbers of pores and cracks were obviously *** results revealed that the hydrogen charging can simultaneously decrease the tensile strength and ductility of the *** with the uncharged sample,the tensile yield strength,ultimate tensile strength and the elongation ratio to failure were respectively reduced by 5.7%,7.3%,31.7%for the 3h-charged sample and 24.6%,24.8%,67.0%for the 18h-charged *** analysis indicated that hydrogen charging can induce the brittle cracking of the alloy and the size of brittle cracking region being composed of quasi-cleavage facets and interfacial cracks on the fracture surfaces was increased with the hydrogen charging time.

关键词： Magnesium-lithium alloy Microstructure Hydrogen-induced damage Hydrogen embrittlement Mechanical behavior

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LaVO_(4)prepared by a high-yield method for superior catalysis to the hydrogen storage of MgH_(2)

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Journal of Magnesium and Alloys 2025年第2期13卷 613-625页

作者： Meihong Wu Mingxia Gao Shanqing Qu Yongfeng Liu Wenping Sun Xin Zhang Chu Liang Xiaoyu Zhang Yaxiong Yang Hongge Pan State Key Laboratory of Silicon and Advanced Semiconductor Materials Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province&School of Materials Science and EngineeringZhejiang UniversityHangzhou 310027PR China Institute of Science and Technology for New Energy Xi'an Technological UniversityXi'an 710021PR China Zhejiang Carbon Neutral Innovation Institute Zhejiang University of TechnologyHangzhou 310014PR China

MgH_(2)is a promising solid-state hydrogen storage ***,its high thermodynamics and sluggish kinetics hinder its practical *** strategy is effective in improving its kinetic ***,the highly efficient catalysts or additives are normally of low-yield in fabrication with high *** this work,a novel structural LaVO_(4)fabricated by a low-cost method of spraying dry followed by a calcination is used as a catalytic additive for the hydrogen storage of MgH_(2).With an optimized addition of LaVO_(4),the overall hydrogen storage performances of MgH_(2)are significantly *** onset dehydrogenation temperature of only 183℃is obtained after an initial activation of dehydrogenation and *** system can desorb 5.7 wt%H_(2)at 250℃within 10 min and maintains a dehydrogenation capacity of 5.0 wt%H_(2)after 50 *** is found that LaVO_(4)is transferred to lanthanum hydride and metallic vanadium in the initial dehydrogenation process,the former acts as a highly effective catalyst for the hydrogen storage of MgH_(2)and the latter undergoes reversible hydrogenation and dehydrogenation in the subsequent *** structural design of the catalyst and its scalable fabrication are highly valuable in realizing the practical application of catalytic strategy for the hydrogen storage of MgH_(2).

关键词： Magnesium hydride Hydrogen storage properties Catalysis,Bimetallic oxide Spray drying

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Strength and toughness mechanism of single Ti microalloyed steels

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Journal of Iron and Steel Research International 2025年第3期32卷 769-782页

作者： Yi Wang Zhi-chao Che Yu-feng Chen Shu-feng Yang Jun-fen Zhang Qi-he Xue School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing100083China State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing100083China HBIS Group Chengde Steel Company Chengde067000HebeiChina

The mechanism of strength and toughness variation in Ti microalloyed steel within the range of 0.04–0.157 wt.%was *** adding 0.13 wt.%Ti,the steel achieves higher strength while maintaining a certain level of elongation and low-temperature impact *** increasing Ti content,the grain size in the steel decreased from 17.7 to 8.9μ*** decrease in grain size is accompanied by an increase in the percentage of low-angle grain boundaries and dislocations,which act as barriers to hinder crack *** Ti microalloyed steel exhibits a 20%increase in yield strength and a 14%increase in tensile *** transformation of steel plasticity occurs when the Ti content exceeds 0.102 wt.%.The low-temperature impact toughness of the steel gradually decreases with increasing Ti *** low Ti content,the low-temperature impact toughness is reduced due to crack initiation by large-size *** high Ti content,the low-temperature impact toughness of the steel deteriorates due to several *** include the narrower tough–brittle transition zone,grain boundary embrittlement caused by small-sized grains,and the decrease in the solid solution strengthening effect.

关键词： Ti microalloyed steel Second phase Tensile property Low-temperature impact property Strengthening mechanism

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Simulation and Experimental Analysis of Contactless Chip Pickup Process Based on a Vortex Flow Gripper

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IEEE Transactions on Semiconductor Manufacturing 2025年第2期38卷 324-331页

作者： Zhai, Peiran Xu, Zhoulong Yin, Zhouping Li, Xiaohang Xie, Bin Wu, Hao Institute for Advanced Electronics Manufacturing State Key Laboratory of Intelligent Manufacturing Equipment and Technology Huazhong University of Science and Technology Wuhan430074 China Wuhan Chiplet Technology Company Ltd. Wuhan430074 China King Abdullah University of Science and Technology Advanced Semiconductor Laboratory Thuwal23955 Saudi Arabia Institute for Advanced Electronics Manufacturing State Key Laboratory of Intelligent Manufacturing Equipment and Technology School of Integrated Circuits Huazhong University of Science and Technology School of Mechanical Science and Engineering Wuhan430074 China

As the preceding process of chip-to-wafer (C2W) hybrid bonding, die pick-up, and transfer are critical in 3D heterogeneous integration (3D HI) technique. Especially, with the ever-shrinking die thickness and ever-increasing bumps on the die surface, mechanical scratches and electrostatic interference on chips caused by the traditional contact-type pickup process cannot be tolerated. Therefore, it is the trend to implement contactless pickup head to realize damage-free chip transfer. Herein, a contactless, pneumatic pickup head based on vortex flow was designed for the efficient and contactless grab of 50 μm ultrathin chips. A baffle structure on the four corners of pickup head was designed, which can achieve stable noncontact pickup of target chip and maintain the position under multiangle loading conditions. Furthermore, we optimized baffle structure to reduce the oscillation of the chip by more than 50%. We explored the underlying mechanism of pneumatic noncontact pickup through computational fluid dynamics (CFD) simulation by three turbulence models. Further, a high-precision vortex platform was built to investigate the pickup force characteristics, radial pressure distribution, and oscillations for different intake pressure and their influence on the noncontact pickup effect. Eventually, the simulation and experimental results indicate that the optimal intake pressure for stable non-contact pickup is between 20 and 30 kPa. This study provides design and optimization methods for stable noncontact picking of microchips, offering theoretical and experimental basis for selecting the optimal air intake pressure in practical applications. © 1988-2012 IEEE.

关键词： Vortex flow

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