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Magnesium Technology Symposium held at the TMS Annual Meeting and Exhibition, 2024

作者： Mc Arthur Sehar, Daniel Telgerafchi, Armaghan Ehsani Iurkovskyi, Artem Opoku, Emmanuel Powell, Adam Materials Science and Engineering Program Department of Mechanical Engineering Worcester Polytechnic Institute WorcesterMA United States Department of Mechanical Engineering Worcester Polytechnic Institute WorcesterMA United States

ISBN: (纸本)9783031502392

MagnesiumMagnesium metal has been significantly used in commercial applications from automobiles to aluminum alloys to defense weaponry. The surge in structural usage of magnesium over the past years has been due to high strength and excellent stiffness-to-weight ratio. RecyclingRecycling magnesium scrap is a crucial aspect of the sustainability of the economy and environmental welfare. G-METS is an advanced distillationDistillation system used in the conversion of low-grade magnesium scrap into high-purityHigh-purity magnesium metal. This multiple-effect system uses the weight of magnesiumMagnesium as a compressor, to build pressure differences between each effect of the condenser-evaporator, modifying boiling points, and enabling transfer of vaporization enthalpy. This system is exceptionally efficient compared to the energy-intensive conventional distillationDistillation technique. This study compares experiments and models of one- and two-effect distillers. © The Minerals, Metals & materials Society 2024.

关键词： Magnesium alloys

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Reuse of sodium–doped iridium oxide nanoparticles as a bio–stimulating electrode by a chemical and electrochemical recovery process

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Ceramics International 2024年第4期50卷 6220-6228页

作者： Tso, Kuang-Chih Chen, Chieh-Hsuan Chen, Po-Chun Li, Shao-Sian Chen, Jeng-Lung Ohta, Jun Wu, Pu-Wei Division of Materials Science Graduate School of Science and Technology Nara Institute of Science and Technology Nara630-0192 Japan Graduate Degree Program of Science and Technology of Accelerator Light Source National Yang Ming Chiao Tung University Hsinchu300 Taiwan Department of Materials Science and Engineering National Yang Ming Chiao Tung University Hsinchu300 Taiwan Institute of Materials Science and Engineering National Taipei University of Technology Taipei106 Taiwan National Synchrotron Radiation Research Center Hsinchu300 Taiwan

A sequential chlorination and electrochemical reduction process is demonstrated to convert Na–doped iridium oxide nanoparticles into useful IrIIICl63−(aq) serving as the precursor for the fabrication of bio–stimulating electrode. The Na–doped iridium oxide nanoparticles are treated in 35 wt% hydrochloric acid at 70 °C for 18 h to form IrIVCl62−(aq) with pH of 0.3, so the latter could be readily reduced to IrIIICl63−(aq) at a potentiostatic mode of 0.6 V (vs. SCE). The oxidation state and the nature of complexing ligands for the regenerated IrIIICl63− and IrIVCl62−, as well as commercially available IrIIICl63− are validated by X–ray Absorption Spectroscopy. UV–Vis profiles of regenerated IrIVCl62−(aq) are recorded and the absorbance at 487 nm signal is benchmarked against that of standard IrIVCl62−(aq) to obtain the effective regeneration ratio of 68.6%. X–ray diffraction patterns of Na–doped iridium oxide nanoparticles before and after the annealing treatment indicate the amorphous structure facilitates the chlorination step. The regenerated IrIIICl63− is reused to synthesize Na–doped iridium oxide thin film serving as a bio–stimulating electrode for implantable bio–electronics. The regenerated Na–doped iridium oxide thin film reveals a charge-storage capacity of 0.32 mC/cm2-nm and impressive stability that are comparable to those of fresh Na–doped iridium oxide thin film derived from commercially available IrIIICl63−. © 2023 Elsevier Ltd and Techna Group S.r.l.

关键词： Transition metal oxides

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Zwitterionic peptides:Tunable next-generation stealth nanoparticle modifications

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Bioactive materials 2023年第9期27卷 113-124页

作者： Clyde Overby Soomin Park Austin Summers Danielle S.W.Benoit Department of Biomedical Engineering University of Rochester RochesterNYUSA Center for Musculoskeletal Research University of RochesterRochesterNYUSA Department of Biology University of Rochester RochesterNYUSA Department of Biology Duquesne UniversityPAUSA Department of Chemical Engineering University of RochesterRochesterNYUSA Materials Science Program University of RochesterRochesterNYUSA Knight Campus for Accelerating Scientific Impact Department of BioengineeringUniversity of OregonEugeneORUSA

Adsorption of proteins to nanoparticles(NPs),a complex process that results in a protein corona,is controlled by NP surface properties that define NP interactions in *** to control adsorbed protein quantity through surface modification have led to improvements in circulation time or ***,current approaches have yet to be identified to control adsorbed protein identities within the ***,we report the development and characterization of diverse zwitterionic peptides(ZIPs)for NP anti-fouling surface functionalization with specific and controllable affinity for protein adsorption profiles defined by ZIP *** serum exposure of ZIP-conjugated NPs and proteomics analysis of the resulting corona,we determined that protein adsorption profiles depend not on the exact composition of the ZIPs but on the sequence and order of charges along the sequence(charge motif).These findings pave the way for developing tunable ZIPs to orchestrate specific ZIP-NP protein adsorption profiles as a function of ZIP charge motif to better control cell and tissue specificity and pharmacokinetics and provide new tools for investigating relationships between protein corona and biological ***,overall ZIP diversity enabled by the diversity of amino acids may ameliorate adaptive immune responses.

关键词： Nanoparticles Protein corona Surface functionalization Peptide design Cellular uptake

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Soft Artificial Synapse Electronics

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Research 2024年第4期8卷 101-118页

作者： Md.Rayid Hasan Mojumder Seongchan Kim Cunjiang Yu Department of Electrical Engineering The Pennsylvania State UniversityUniversity ParkPA 16802USA Department of Electrical and Systems Engineering University of PennsylvaniaPhiladelphiaPA 19104USA Department of Electrical and Computer Engineering University of IllinoisUrbana-ChampaignUrbanaIL 61801USA Department of Materials Science and Engineering University of IllinoisUrbana-ChampaignUrbanaIL 61801USA Department of Mechanical Science and Engineering University of IllinoisUrbana-ChampaignUrbanaIL 61801USA Department of Bioengineering University of IllinoisUrbana-ChampaignUrbanaIL 61801USA Materials Research Laboratory University of IllinoisUrbana-ChampaignUrbanaIL 61801USA Beckman Institute for Advanced Science and Technology University of IllinoisUrbana-ChampaignUrbanaIL 61801USA Nick Holonyak Micro and Nanotechnology Laboratory University of IllinoisUrbana-ChampaignUrbanaIL 61801USA

Soft electronics,known for their bendable,stretchable,and flexible properties,are revolutionizing fields such as biomedical sensing,consumer electronics,and robotics.A primary challenge in this domain is achieving low power consumption,often hampered by the limitations of the conventional von Neumann *** response,the development of soft artificial synapses(SASs)has gained substantial *** synapses seek to replicate the signal transmission properties of biological synapses,offering an innovative solution to this *** review explores the materials and device architectures integral to SAS fabrication,emphasizing flexibility and stability under mechanical *** architectures,including floating-gate dielectric,ferroelectric-gate dielectric,and electrolyte-gate dielectric,are analyzed for effective weight control in *** utilization of organic and low-dimensional materials is highlighted,showcasing their plasticity and energy-efficient ***,the paper investigates the integration of functionality into SASs,particularly focusing on devices that autonomously sense external *** SASs,capable of recognizing optical,mechanical,chemical,olfactory,and auditory cues,demonstrate promising applications in computing and sensing.A detailed examination of photo-functionalized,tactile-functionalized,and chemoreception-functionalized SASs reveals their potential in image recognition,tactile sensing,and chemosensory applications,*** study highlights that SASs and functionalized SAS devices hold transformative potential for bioelectronics and sensing for soft-robotics applications;however,further research is necessary to address scalability,longtime stability,and utilizing functionalized SASs for prosthetics and in vivo applications through clinical *** providing a comprehensive overview,this paper contributes to the understanding of SASs,bridging research gaps and paving the way tow

关键词： dielectric utilizing gained

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Carbon nanofiber catalysts containing high-entropy metal phosphides with low-content Ru for highly efficient hydrogen evolution reaction

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Rare Metals 2025年第1期44卷 324-335页

作者： Peng Wang Jie Zheng Xue-Hao Li Wen-Bo Cui Jin-Hua Liu Yong Wan Jun Zhang Yusuke Yamauchi Zhong-Li Wang Mang Niu Yun-Ze Long Shandong Key Laboratory of Medical and Health Textile Materials College of PhysicsQingdao UniversityQingdao 266071China Industrial Research Institute of Nonwovens and Technical Textiles Shandong Center for Engineered Nonwovens(SCEN)College of Textiles ClothingQingdao UniversityQingdao 266071China State Key Laboratory of Bio-Fibers and Eco-textiles Institute of Biochemical EngineeringCollege of Materials Science and EngineeringQingdao UniversityQingdao 266071China School of Chemical Engineering and Australian Institute for Bioengineering and Nanotechnology(AIBN) The University of QueenslandBrisbaneQLD 4072Australia Department of Chemical and Biomolecular Engineering Yonsei UniversitySeoul 03722Republic of Korea Department of Materials Process Engineering Graduate School of EngineeringNagoya UniversityNagoya 464-8603Japan Tianjin Key Laboratory of Applied Catalysis Science and Technology School of Chemical Engineering and TechnologyTianjin UniversityTianjin300072China

High-entropy metal phosphide(HEMP)has considerable potential as an electrocatalyst owing to its beneficial properties,including high-entropy alloy synergy as well as the controllable structure and high conductivity of ***,electrospinning and in situ phosphating were employed to prepare three-dimensional(3D)networks of self-supporting HEMP nanofibers with varying degrees of phosphate *** characterizations via X-ray diffraction and X-ray photoelectron spectroscopy,as well as density functional theory calculations,demonstrate that the introduction of phosphorus(P)atoms to HEMP carbon nanofibers mediates their electronic structure,leads to lattice expansion,which in turn enhances their catalytic performance in the hydrogen evolution reaction(HER).Moreover,the formation of metal-P bonds weakens metal-metal interaction and decreases the free energy of hydrogen adsorption,contributing to the exceptional activity observed in the HEMP *** measurements demonstrate that the HEMP-0.75 catalyst with an ultralow loading of 1.22 wt%ruthenium(Ru)exhibits the highest HER catalytic activity and stability in a 1 M KOH electrolyte,achieving a minimal overpotential of 26 mV at a current density of 10 mA·cm^(-2)and Tafel slope of 50.9 mV·dec^(-1).

关键词： High-entropy metal phosphide Electrospinning Hydrogen evolution reaction Self-supporting carbon nanofibers

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Macroscopic Discolorization in Quantum Dot Color Converters for Microdisplay Applications

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ACS Applied Nano materials 2024年第7期7卷 8258-8268页

作者： Lin, Chen-Te Chen, Hsueh-Shih Ph.D. Program in Prospective Functional Materials Industry College of Engineering National Tsing Hua University Hsinchu30013 Taiwan Department of Materials Science and Engineering National Tsing Hua University Hsinchu30013 Taiwan College of Semiconductor Research National Tsing Hua University Hsinchu30013 Taiwan

Quantum dot color converters (QDCCs) currently have the unsolved problems of photostability and discolorization in appearance after long-term operation in microdisplays. Instead of polymer-to-carbon conversion and/or impurity precipitation, the macroscopic bright-yellow-to-dark-brown discolorization is determined by microscopic interfacial chemical reactions of the QD-ligand-polymer system. The phenomenon has been confirmed to be related to multiple factors, including chemical transformation of the QD shell and partial degradation of the polymer, resulting in increased optical reflectance and reduced photoluminescence (PL) intensity in QDCCs. Our finding suggests that the photoexcitation of QDs in the polymer matrix should lead to detached surface ligands along with photocatalytic reactions, oxidizing the QD shell together with degrading the polymer chains. © 2024 The Authors. Published by American Chemical Society

关键词： Color

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Low-Temperature Methanolysis of Polycarbonate over Solid Base Sodium Aluminate

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Langmuir 2024年第10期40卷 5338-5347页

作者： Krisbiantoro, Philip Anggo Sato, Miyu Lin, Tzu-Ming Chang, Yu-Chia Peng, Tzu-Yun Wu, Yun-Chih Liao, Weisheng Kamiya, Yuichi Otomo, Ryoichi Wu, Kevin C.-W. Molecular Science and Technology Program Taiwan International Graduate Program Academia Sinica Taipei11529 Taiwan International Graduate Program of Molecular Science and Technology National Taiwan University Taipei10617 Taiwan Department of Chemical Engineering College of Engineering National Taiwan University Taipei10617 Taiwan Graduate School of Environmental Science Hokkaido University Nishi 5 Kita 10 Sapporo060-0810 Japan Faculty of Environmental Earth Science Hokkaido University Nishi 5 Kita 10 Sapporo060-0810 Japan Center of Atomic Initiative for New Materials National Taiwan University Taipei10617 Taiwan Department of Chemical Engineering and Materials Science Yuan Ze University Taoyuan320 Taiwan

Herein, a low-cost and readily available sodium aluminate (NaAlO2) was used as a solid base catalyst for the depolymerization of polycarbonate (PC) via methanolysis in the presence of tetrahydrofuran (THF) as a solvent. NaAlO2 was highly active for the reaction, and the performance was comparable to that of soluble strong base SrO and much higher than those of MgO and CaO. By the reaction over the catalyst, a highly pure and crystalline bisphenol A (BPA) was obtained. Among tested organic solvents, THF was the best in aiding PC methanolysis over NaAlO2 due to the polarity similar to PC according to Hansen solubility parameters (HSPs). At 60 °C, 98.1% PC conversion and 96.8% BPA yield were achieved within just 2 h. NaAlO2 was reusable without any severe catalyst deactivation in at least four runs. The mechanistic study revealed that the reaction proceeded via the methoxide pathway, with THF aiding the dissolution of PC. The reaction over NaAlO2 possessed a low apparent activation energy (Ea) of 75.1 kJ mol-1, which is the lowest ever reported so far for the reaction over solid catalysts. © 2024 The Authors. Published by American Chemical Society.

关键词： Sodium Aluminate

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Mutual Self‑Regulation of d‑Electrons of Single Atoms and Adjacent Nanoparticles for Bifunctional Oxygen Electrocatalysis and Rechargeable Zinc‑Air Batteries

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Nano-Micro Letters 2023年第4期15卷 40-57页

作者： Sundaram Chandrasekaran Rong Hu Lei Yao Lijun Sui Yongping Liu Amor Abdelkader Yongliang Li Xiangzhong Ren Libo Deng College of Chemistry and Environmental Engineering Shenzhen UniversityShenzhen 518060People’s Republic of China College of Chemistry and Bioengineering Guilin University of TechnologyGuilin 541004People’s Republic of China Shenzhen Key Laboratory of Special Functional Materials Shenzhen Engineering Laboratory for Advanced Technology of CeramicsCollege of Materials Science and EngineeringGuangdong Research Center for Interfacial Engineering of Functional MaterialsShenzhen UniversityShenzhen 518060People’s Republic of China Shanghai Key Laboratory for R&D and Application of Metallic Functional Materials Institute of New Energy for VehiclesSchool of Materials Science and EngineeringTongji UniversityShanghai 201804People’s Republic of China Department of Design and Engineering Faculty of Science&TechnologyBournemouth UniversityPoole BH125BBDorsetUK

Rechargeable zinc-air batteries(ZABs)are a promising energy conversion device,which rely critically on electrocatalysts to accelerate their rate-determining reactions such as oxygen reduction(ORR)and oxygen evolution reactions(OER).Herein,we fabricate a range of bifunctional M-N-C(metal-nitrogen-carbon)catalysts containing M-Nx coordination sites and M/MxC nanoparticles(M=Co,Fe,and Cu)using a new class ofγ-cyclodextrin(CD)based metal-organic framework as the *** the two types of active sites interacting with each other in the catalysts,the obtained Fe@C-FeNC and Co@C-CoNC display superior alkaline ORR activity in terms of low half-wave(E1/2)potential(~0.917 and 0.906 V,respectively),which are higher than Cu@C-CuNC(~0.829 V)and the commercial Pt/C(~0.861 V).As a bifunctional electrocatalyst,the Co@C-CoNC exhibits the best performance,showing a bifunctional ORR/OER overpotential(ΔE)of~0.732 V,which is much lower than that of Fe@C-FeNC(~0.831 V)and Cu@C-CuNC(~1.411 V),as well as most of the robust bifunctional electrocatalysts reported to *** X-ray absorption spectroscopy and density functional theory simulations reveal that the strong electronic correlation between metallic Co nanoparticles and the atomic Co-N4 sites in the Co@C-CoNC catalyst can increase the d-electron density near the Fermi level and thus effectively optimize the adsorption/desorption of intermediates in ORR/OER,resulting in an enhanced bifunctional electrocatalytic *** Co@C-CoNC-based rechargeable ZAB exhibited a maximum power density of 162.80 mW cm^(−2) at 270.30 mA cm^(−2),higher than the combination of commercial Pt/C+RuO2(~158.90 mW cm^(−2) at 265.80 mA cm^(−2))*** the galvanostatic discharge at 10 mA cm^(−2),the ZAB delivered an almost stable discharge voltage of 1.2 V for~140 h,signifying the virtue of excellent bifunctional ORR/OER electrocatalytic activity.

关键词： Cyclodextrin CD-MOF Single-atom catalyst ORR/OER Zinc-air battery

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Giant phonon-skyrmion coupling in ferromagnet/heavy metal heterostructures

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Physical Review B 2024年第6期110卷 064423-064423页

作者： Egor Savostin Vitaliy Lomakin Program in Materials Science and Engineering Center for Memory and Recording Research Department of Electrical and Computer Engineering

The strong impact of the strain-induced Dzyaloshinskii-Moriya interaction (SIDMI) on the magnetization dynamics of skyrmions in nanomagnetic structures is demonstrated. The effects of SIDMI are characterized by skyrmion equations (SEs) of motion and magnetoelastic (ME) equations. The study is performed on a model system of MgO/CoFe/Pt stacked on a piezoelectric substrate. The results demonstrate a major nonlinear amplification in both the first- and higher-harmonic magnitudes of the skyrmion breathing mode due to SIDMI. Remarkably, this enhancement can trigger a skyrmion collapse, enabling its deletion with ultraweak strain-induced excitations. The SIDMI effect is shown to be much more significant than the conventional ME effect. These findings open different avenues for the efficient manipulation of nanomagnetic structures through strain.

关键词： Exchange interaction Magnetic interactions Magnetization dynamics Magnetoacoustic effect Micromagnetism Spin dynamics

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Exploring the Correlation Between Surface Roughness, Surface Energy, Nano-indentation, Electrical Properties, and Magnetic Characteristics of Annealed Co40Fe40Dy20 Thin Films Deposited on Si(100) Substrates

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Journal of Electronic materials 2024年第8期53卷 4498-4511页

作者： Liu, Wen-Jen Chang, Yung-Huang Hsu, Shuo-Ting Fern, Chi-Lon Chen, Yuan-Tsung Tsao, Shin-Ying Lin, Shih-Hung Department of Materials Science and Engineering I-Shou University Kaohsiung840 Taiwan Bachelor Program in Industrial Technology National Yunlin University of Science and Technology 123 University Road Section 3 Yunlin Douliou64002 Taiwan Graduate School of Materials Science National Yunlin University of Science and Technology 123 University Road Section 3 Yunlin Douliou64002 Taiwan Department of Electronic Engineering National Yunlin University of Science and Technology 123 University Road Section 3 Yunlin Douliou64002 Taiwan

The impact of film thickness and annealing temperature on the structural, electrical, magnetic, and mechanical properties of cobalt–iron–dysprosium (Co40Fe40Dy20 ) thin films deposited on Si(100) substrates have been investigated. X-ray diffraction (XRD) analysis confirmed the film's crystalline microstructure, featuring dysprosium oxide, Dy2O3(440), and cobalt oxide, Co2O3(422) and Co2O3(511), crystallographic phases. Surface energy measurements indicated a noticeable reduction in surface energy following annealing treatments, which could be ascribed to the alleviation of residual stress and enhanced atomic arrangement, resulting in a more stable film structure with reduced surface energy. The film exhibited a decreasing trend in hardness with increasing thickness, and film resistivity was significantly responsive to alterations in thickness and annealing temperature. Notably, the Co40Fe40Dy20 film demonstrated exceptional characteristics, featuring a high saturation magnetization (Ms) of 675 emu/cm3 and a low coercivity (Hc) of 9.5 Oe. Further analysis of magnetic domains and hysteresis loops revealed that larger and brighter domains were associated with higher Hc. To sum up, the surface roughness of CoFeDy films under various annealing temperatures played a pivotal role in shaping their magnetic, electrical, adhesive, and optical characteristics. An improved low-frequency alternating current magnetic susceptibility (χac) value was achieved by minimizing the pinning effect on domain walls through surface smoothing. Moreover, smoother surfaces displayed heightened carrier conductivity, resulting in a decrease in electrical resistance. On the whole, Co40Fe40Dy20 films exhibited outstanding soft magnetic properties, encompassing high saturation magnetization, low coercivity, exceptional mechanical attributes, and decreased surface energy. Graphical Abstract: (Figure presented.) © The Minerals, Metals & materials Society 2024.

关键词： Magnetic susceptibility

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