Al-Sc alloys with high Sc contents are served as sputtering targets for making high-performance piezoelectric *** micro structure of these alloys would affect the sputtering process and the final quality of the functi...
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Al-Sc alloys with high Sc contents are served as sputtering targets for making high-performance piezoelectric *** micro structure of these alloys would affect the sputtering process and the final quality of the functional *** this study,the microstructure in as-c as ted Al-20%Sc(in atomic ratio)alloys is characterized and the feathery Al3Sc grains with twin relationships are reported for the first *** crystallographic features of twined structures and growth directions are quantitatively analyzed by electron backscatter diffraction(EBSD)technique.
FeCrAlCu,FeCrAlCuNi,FeCrAlCuCo,and FeCrAlCuNiCo high-entropy alloy(HEA)coatings were synthesized on the surface of 45#steel through cold spraying-assisted laser *** reveal that all four HEA coatings are composed of fa...
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FeCrAlCu,FeCrAlCuNi,FeCrAlCuCo,and FeCrAlCuNiCo high-entropy alloy(HEA)coatings were synthesized on the surface of 45#steel through cold spraying-assisted laser *** reveal that all four HEA coatings are composed of face-centered cubic+body-centered cubic ***,the microstructure of the coatings consists of columnar *** the simultaneous addition of both Ni and Co elements,the columnar dendritic grains are gradually refined in the ***,the FeCrAlCuNiCo HEA coating exhibits excellent friction performance with the coating hardness of 5847.7 MPa,friction factor of 0.45,and wear rate of 3.72×10^(−5) mm^(3)·N^(−1)·m^(−1).The predominant wear mechanism is the adhesive wear and abrasive wear.
Driven by the serious ecological problems,it is urgent to explore high-efficiency sustainable energy *** electrocatalysis acts as important half-reactions in the emerging electrochemical energy techniques including el...
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Driven by the serious ecological problems,it is urgent to explore high-efficiency sustainable energy *** electrocatalysis acts as important half-reactions in the emerging electrochemical energy techniques including electrolysis and *** composites exhibit the merits of rich porous,superior hydrophilic,and large specific surface area,which can significantly improve the electrolyte penetration and boost the kinetics process of oxygen *** this invited contribution,the advances and challenges of a novel gel materials for oxygen electrocatalysis are *** from the structure-activity-performance relationship of gel materials,synthetic routes of nanostructured gel materials,namely,radical polymerization,sol-gel method,hydrothermal/solvothermal reactions,and ligand-substitution method,are ***,the gel composites are divided into polymer-based,metal-based,and carbon-based materials in turn,and their applications in oxygen electrocatalysis are discussed *** the end,the perspective and challenges for advanced gel oxygen electrocatalysts are proposed.
With the proposal of a“smart battery,”real-time sensing by rechargeable batteries has become progressively more important in both fundamental research and practical ***,many traditional sensing technologies suffer f...
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With the proposal of a“smart battery,”real-time sensing by rechargeable batteries has become progressively more important in both fundamental research and practical ***,many traditional sensing technologies suffer from low sensitivity,large size,and electromagnetic interference problems,rendering them unusable in the harsh and complicated electrochemical environments of *** optical sensor is an alternative approach to realize multiple-parameter,multiple-point measurements ***,it has garnered significant *** analyzing these measured parameters,the state of interest can be decoded to monitor a battery's *** review summarizes current progress in optical sensing techniques for batteries with respect to various sensing parameters,discussing the current limitations of optical fiber sensors as well as directions for their future development.
β-Amyloid(Aβ)peptide fibrillation,one of the characteristic hallmarks of Alzheimer’s disease,is determined by many interfacial physical-chemical factors,e.g.,charge,hydrophobicity,*** extensive research,chiral effe...
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β-Amyloid(Aβ)peptide fibrillation,one of the characteristic hallmarks of Alzheimer’s disease,is determined by many interfacial physical-chemical factors,e.g.,charge,hydrophobicity,*** extensive research,chiral effect in different-scales on the fibrillation process of Aβremains ***,molecular-scale,sub-nanoscale,and nanoscale chiral-structures were constructed to investigate their chiral effect on the fibrillation of Aβ_(40) *** structures from molecular-scale to nanoscale were obtained from the different periods of the chemosynthesis process of chiral ZnS quantum-dots(QDs),confirmed by real-time monitoring of circular dichroism *** molecular-scale,both L-penicillamine(L-P)and D-P ligands accelerated the fibrillation of Aβ_(40),and the speed-up effect of D-P was slightly stronger than *** sub-nanoscale,both two chiral Zncomplexes(L-Zn and D-Zn)induced the agglomeration of Aβ_(40) without chirality *** nanoscale,both L-ZnS and DZnS QDs inhibited the fibrillation of Aβ_(40),and the inhibition effect of L-ZnS was notably better than that of ***-situ kinetics experiments of Aβ_(40) co-incubated with two chiral QDs demonstrated that L-ZnS completely prevents the misfolding of Aβ_(40) from unfolded toβ-sheet,while D-ZnS cannot achieve *** site-replacement experiments and simulation results revealed the underlying molecular mechanisms of the different inhibition efficiency of chiral ZnS QDs on Aβ_(40) fibrillation,which mainly attribute to the stereoselectivity interaction between the chiral ligands of ZnS QDs and electro-positive amino acid residues(R5,K16,and K28)of Aβ_(40).This work offers a microscopic insight of chiral effect on Aβfibrillation exerted by structures in different-scales,and provides a guidance in precise regulation of protein fibrillation via manipulating chiral structures in different-scales.
The fracture toughness(KIC)of high-entropy oxides(HEOs)is critically important for several applications,but identification and quantification of the toughening mechanisms resulting from latticeengineering/distortion i...
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The fracture toughness(KIC)of high-entropy oxides(HEOs)is critically important for several applications,but identification and quantification of the toughening mechanisms resulting from latticeengineering/distortion in HEOs is ***,based on the classic Griffith criteria,a physicsdriven theoretical equation combined with a knowledge-enabled data-driven machine-learning algorithm is proposed to predict the KIC and elucidate the toughening mechanisms of A_(2)Zr_(2)O_(7)-type *** with experimental verification,our proposed model is applied to a dataset comprising 41208(nRE1/n)_(2)Zr_(2)O_(7)(n=2~7)HEOs,considering the contributions of the intrinsic brittleness and increased toughness due to the local lattice distortion(LLD),thereby addressing the challenge of accurate estimating KIC in complex HEOs using the rule of *** crack tip propagation,the interaction mechanism of cations induces stress fields and charge variations of LLD and dissipates crack energy,thus,to yield the crack tip softening and the elastic shielding and to enhance the toughness of HEOs.
The pursuit of healthy aging has long rendered aging and senescence ***-related ailments,such as cardiovascular diseases,diabetes,and neurodegenerative disorders,pose significant threats to *** studies have shed light...
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The pursuit of healthy aging has long rendered aging and senescence ***-related ailments,such as cardiovascular diseases,diabetes,and neurodegenerative disorders,pose significant threats to *** studies have shed light on the intricate mechanisms encompassing genetics,epigenetics,transcriptomics,and metabolomics in the processes of senescence and aging,as well as the establishment of age-related *** these underlying mechanisms governing aging and related pathology metabolism assumes a pivotal role that holds promise for intervention and *** advancements in metabolomics techniques and analysis methods have significantly propelled the study of senescence and aging,particularly with the aid of multiscale metabolomics which has facilitated the discovery of metabolic markers and therapeutic *** review provides an overview of senescence and aging,emphasizing the crucial role metabolism plays in the aging process as well as age-related diseases.
The simultaneous detection of multiple stimuli,such as pressure and temperature,has long been a persistent challenge for developing electronic skin(eskin)to emulate the functionality of human ***,the demand for integr...
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The simultaneous detection of multiple stimuli,such as pressure and temperature,has long been a persistent challenge for developing electronic skin(eskin)to emulate the functionality of human ***,the demand for integrated power supply units is an additional pressing concern to achieve its lightweightness and ***,we propose a self-powered dual temperature–pressure(SPDM)sensor,which utilizes a compressible ionic gel electrolyte driven by the potential difference between MXene and Al *** SPDM sensor exhibits a rapid and timely response to changes in pressure-induced deformation,while exhibiting a slow and hysteretic response to temperature *** distinct response characteristics enable the differentiation of current signals generated by different stimuli through machine learning,resulting in an impressive accuracy rate of 99.1%.Furthermore,the developed SPDM sensor exhibits a wide pressure detection range of 0–800 kPa and a broad temperature detection range of 5–75C,encompassing the environmental conditions encountered in daily human *** dual-mode coupled strategy by machine learning provides an effective approach for temperature and pressure detection and discrimination,showcasing its potential applications in wearable electronics,intelligent robots,human–machine interactions,and so on.
The thermal diffusivity and specific heat capacity of continuous casting (SC) and high-pressure diecasting (HPDC) aluminum alloys before and after T4 and T6 heat treatments were measured at room temperature, and their...
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Intensity modulation/direct detection(IM/DD) optical fiber communication system is an appropriate candidate for optical interconnect applications due to its low cost and low power consumption characteristics [1]. 4-le...
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Intensity modulation/direct detection(IM/DD) optical fiber communication system is an appropriate candidate for optical interconnect applications due to its low cost and low power consumption characteristics [1]. 4-level pulse amplitude modulation(PAM-4) is widely discussed in optical interconnects due to its simpler transceiver configuration and implementation [2].
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