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In situ confined vertical growth of Co_(2.5)Ni_(0.5)Si_(2)O_(5)(OH)_(4)nanoarrays on rGO for an efficient oxygen evolution reaction

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Nano materials Science 2023年第4期5卷 351-360页

作者： Yang Mu Xiaoyu Pei Yunfeng Zhao Xueying Dong Zongkui Kou Miao Cui Changgong Meng Yifu Zhang State Key Laboratory of Fine Chemicals School of Chemical EngineeringDalian University of TechnologyDalian116024China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan430070China

Rational design of oxygen evolution reaction(OER)catalysts at low cost would greatly benefit the *** advantage of earth-abundant elements Si,Co and Ni,we produce a unique-structure where cobalt-nickel silicate hydroxide[Co_(2.5)Ni_(0.5)Si_(2)O_(5)(OH)_(4)]is vertically grown on a reduced graphene oxide(rGO)support(CNS@rGO).This is developed as a low-cost and prospective OER *** to cobalt or nickel silicate hydroxide@rGO(CS@rGO and NS@rGO,respectively)nanoarrays,the bimetal CNS@rGO nanoarray exhibits impressive OER performance with an overpotential of 307 mV@10 mA cm^(-2).This value is higher than that of CS@rGO and NS@*** CNS@rGO nanoarray has an overpotential of 446 mV@100 mA cm^(-2),about 1.4 times that of the commercial RuO_(2)*** achieved OER activity is superior to the state-of-the-art metal oxides/hydroxides and their *** vertically grown nanostructure and optimized metal-support electronic interactions play an indispensable role for OER performance improvement,including a fast electron transfer pathway,short proton/electron diffusion distance,more active metal centers,as well as optimized dualatomic electron *** advantage of interlay chemical regulation and the in-situ growth method,the advanced-structural CNS@rGO nanoarrays provide a new horizon to the rational and flexible design of efficient and promising OER electrocatalysts.

关键词： Co_(2.5)Ni_(0.5)Si_(2)O_(5)(OH)_(4)@rGO Vertical grown nanoarrays Geometric and electronic structure regulation Metal-support interactions Oxygen evolution reaction

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Isomeric Fluorene-based Heteroundecenes with Different Side Chains Anchoring Positions for Small Molecule Acceptors

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Journal of Wuhan University of technology(materials Science) 2022年第1期37卷 136-147页

作者： WANG Wei ZHAN Chun XIAO Shengqiang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

Two isomeric fluorene-based heteroundecenes of bis(thienocyclopenthieno[3,2-b]thieno)fluorene(BT2T-F)and bis(dithieno[3,2-b:2’,3’-d]thiophene)cyclopentafluorene(B3T-F)have been designed and *** side chains of 4-hexylphenyl anchor on the 5th and 8th positions in B3T-F while on the 4th and 9th positions in BT2T-F,in which the former is closer to the center of the fused *** corresponding acceptor-donor-acceptor(A-D-A)type small molecule acceptors(SMAs)of BT2T-FIC and B3T-FIC were prepared by linking BT2T-F and B3T-F as fused ring donor units with the acceptor unit of 2-(5,6-difluoro-3-oxo-2,3-dihydroinden-1-ylidene)malononitrile(IC-2F),respectively.B3T-FIC presents a superior crystallinity with intense face-on π-π stacking in its neat film while BT2T-FIC is more *** blended with PBDB-T-2Cl as a polymer donor,the optimized PBDB-T-2Cl:BT2T-FIC device exhibits an averaged power conversion efficiency(PCE)of 10.56%while only 7.53%in the PBDB-T-2Cl:B3T-FIC *** improved short-circuit current(J_(sc))and fill factor(FF)of the PBDB-T-2Cl:BT2T-FIC device are the main contribution of its higher performance,which is attributed to its more efficient and balanced charge transport and better carrier recombination *** that BT2T-FIC blend and B3T-FIC blend films both take a preferential face-on orientatedπ-πstacking with comparable distances,the suitable SMA domain size obtained in the BT2T-FIC blend could account for its more efficient photovoltaic *** results highlight the importance of side-chain strategy in developing efficient SMAs with huge fused ring cores.

关键词： polymer solar cells small molecule acceptor side chains morphology

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Bioresponsive fluorescent probes active in the second near-infrared window

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iRADIOLOGY 2023年第1期1卷 36-60页

作者： Yuqin Chen Jie Chen Baisong Chang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhanChina

Emerging stimuli-responsive composite probes active in the second nearinfrared window(NIR-II,1000–1700 nm)hold vast potential for improving in vivo imaging performance with minimized noise *** interactions among external irradiation,shell species,and the emissive core are key factors in the design of smart *** external irradiation provides energy for shell species and the emissive core to generate intense NIR-II fluorescence signals,while the energy transfer process hinders NIR-II emission in the inner structure of smart composite ***,if pathophysiological stimuli interrupt the above processes,then NIR-II fluorescence signals are *** review covers NIR-II imaging based on diverse smart composite NIR-II fluorescent probes responding to various biological stimuli,including ONOO−,overexpressed reactive sulfur species,abnormally expressed enzymes,and abnormal levels of physiological ***,to appreciate these advances,the challenges and perspectives of stimuliresponsive composite NIR-II probes are highlighted.

关键词： composite engineering second near-infrared window smart probe stimulus sensitivity pathophysiological microenvironment

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Deep learning-enhanced NIR-II fluorescence volumetric microscopy for dynamic 3D vascular imaging

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Journal of Innovative Optical Health Sciences 2025年第3期18卷 154-164页

作者： Shiyi Peng Yuhuang Zhang Xuanjie Mou Tianxiang Wu Mingxi Zhang Jun Qian State Key Laboratory of Extreme Photonics and Instrumentation International Research Center for Advanced PhotonicsCentre for Optical and Electromagnetic ResearchCollege of Optical Science and EngineeringZhejiang UniversityHangzhou 310058P.R.China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070P.R.China

Three-dimensional (3D) visualization of dynamic biological processes in deep tissue remains challenging due to the trade-off between temporal resolution and imaging depth. Here, we present a novel near-infrared-II (NIR-II, 900–1880nm) fluorescence volumetric microscopic imaging method that combines an electrically tunable lens (ETL) with deep learning approaches for rapid 3D imaging. The technology achieves volumetric imaging at 4.2 frames per second (fps) across a 200 μm depth range in live mouse brain vasculature. Two specialized neural networks are utilized: a scale-recurrent network (SRN) for image enhancement and a cerebral vessel interpolation (CVI) network that enables 16-fold axial upsampling. The SRN, trained on two-photon fluorescence microscopic data, improves both lateral and axial resolution of NIR-II fluorescence wide-field microscopic images. The CVI network, adapted from video interpolation techniques, generates intermediate frames between acquired axial planes, resulting in smooth and continuous 3D vessel reconstructions. Using this integrated system, we visualize and quantify blood flow dynamics in individual vessels and are capable of measuring blood velocity at different depths. This approach maintains high lateral resolution while achieving rapid volumetric imaging, and is particularly suitable for studying dynamic vascular processes in deep tissue. Our method demonstrates the potential of combining optical engineering with artificial intelligence to advance biological imaging capabilities.

关键词： NIR-II fluorescence bioimaging volumetric microscopy deep learning reconstruction dynamic vascular imaging

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Unveiling oscillatory nature for sustainable fuel production

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National Science Review 2024年第5期11卷 90-91页

作者： Ning Han Ye Wang Bao-Lian Su Department of Materials Engineering State Key Laboratory of Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials National Engineering Laboratory for Green Chemical Productions of Alcohols Ethers and Esters College of Chemistry and Chemical Engineering Xiamen University Laboratory of Inorganic Materials Chemistry(CMI) University of Namur State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology

A century ago, in 1923, Franz Fischer and Hans Tropsch introduced the groundbreaking Fischer–Tropsch (FT) synthesis, a heterogeneous catalytic process used to convert synthesis gas (syngas,CO+H2) into multi-carbon hydrocarbons [1]. Over the past 100 years, FT synthesis has emerged as a pivotal method for converting non-petroleum resources into exceptionally clean fuels or valuable chemicals via syngas [2–4].

关键词： production nature fuel oscillatory sustainable unveiling

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The Kirkendall effect on erosion resistance of chrome-coated 25Cr3Mo2WNiV and 30SiMn2MoV gun barrel steels

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Journal of materials Science & technology 2024年第10期177卷 246-255页

作者： C.H.Dou P.F.Jin C.Z.Wang J.J.Li C.Zhang J.F.Huang C.Zhang Key Laboratory for Advanced Materials Processing State State Key Laboratory for Advanced Metals and MaterialsUniversity of Science and Technology BeijingBeijing 100083China National Joint Engineering Research Center for Abrasion Control and Molding of Metal Materials School of Materials Science and EngineeringHenan University of Science and TechnologyLuoyang 471003China

This study aimed to investigate the erosion behavior and mechanism of a newly developed 25Cr3Mo2WNiV steel with a chrome coating using promoted ignition combustion *** erosion threshold pressure and temperature of the chrome-coated 25Cr3Mo2WNiV steel were determined to be 0.2 MPa and 254.3 K higher than those of traditional chrome-coated 30SiMn2MoV ***,Kirkendall voids and inter-diffusion between the Cr coating and matrix were first observed before *** improved erosion resistance of the chrome-coated 25Cr3Mo2WNiV steel was attributed to the suppression of the Kirkendall effect,which minimized heat generation at the Cr/matrix interface by pre-venting oxygen diffusion and reducing oxygen affinity.

关键词： Erosion resistance Kirkendall effect Cr coating Gun steel

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Imaging-guided precision oncotherapy mediated by nanoprobes: From seeing to curing

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Chinese Chemical Letters 2024年第1期35卷 116-128页

作者： Jie Zheng Shi-Hui Chen Biao Huang Mingxi Zhang Quan Yuan Ran Cui College of Chemistry and Molecular Sciences Wuhan UniversityWuhan 430072China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Hubei Jiangxia Laboratory Wuhan 430200China

Malignant tumors are the main diseases threatening human life. Using precise theranostics to diagnose and cure tumors has emerged as a new method to improve patient survival. Based on the current development of precise tumor imaging, image-guided tumor therapy has received widespread attention because it is beneficial for developing precise treatment of tumors, has the potential to improve the efficacy of tumor therapy and reduce the incidence of adverse side effects. Nanoprobes, which are nanomaterial functionalized with specific biomolecules, have intrigued intense interest due to their great potential in monitoring biorecognition and biodetection evens. Benefiting from the unique advantages of nanomaterials, including the easy surface functionalization, the unique imaging performances, and the high drug loading capacity, nanoprobes have become a powerful tool to simultaneously realize tumor precise imaging, diagnosis, and therapy. This review introduces the non-invasive tumor precise imaging and highlights the recent advances of image-guided oncotherapy mediated by nanoprobes in anti-tumor drug delivery, tumor precise surgical navigation, chemodynamic therapy, and phototherapy. Finally, a perspective on the challenge and future direction of nanoprobes in imaging-guided tumor theranostics is also discussed.

关键词： Precise theranostics Imaging-guided Tumor surgical navigation Chemodynamic therapy Phototherapy Nanoprobes

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BiOBr/COF S-scheme photocatalyst for H_(2)O_(2) production via concerted two-electron pathway

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Journal of materials Science & technology 2023年第35期166卷 241-249页

作者： Haozhen Zhang Jingjing Liu Yong Zhang Bei Cheng Bicheng Zhu Linxi Wang Laboratory of Solar Fuel Faculty of Materials Science and ChemistryChina University of Geosciences68 Jincheng StreetWuhan 430078China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

Constructing step-scheme(S-scheme)heterojunctions has become a popular strategy for efficient pho-tocatalytic H_(2)O_(2) ***,we in situ grew BiOBr nanosheets(NSs)on a Schiff-base covalent organic framework(COF)with largeπ-conjugated structures to prepare S-scheme BiOBr/COF photocat-alysts for H_(2)O_(2) *** highest photocatalytic H_(2)O_(2) production performance of the composite sample constituting the S-scheme heterojunction is 3749μmol g−1 h−1,which was 1.85 and 27 times the rates of COF and BiOBr,*** construction of S-scheme heterojunction contributed to ef-ficient carrier transfer and separation in space and enhanced redox ***,the lying-down O_(2)-adsorption configuration on the COF surface favors the concerted two-electron O_(2) reduction process,which greatly reduced the reduction potential requirement for O_(2)-to-H_(2)O_(2) *** synergy be-tween the S-scheme heterojunction and the unique O_(2)-COF interaction boosted photocatalytic H_(2)O_(2) pro-duction activity.

关键词： S-scheme heterojunction Photocatalytic H_(2)O_(2)production Covalent organic frameworks Concerted two-electron O_(2)reduction O_(2)-adsorption configuration

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Catalytic recycling of plastics into value-added products

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Nano Research 2024年第11期17卷 9428-9445页

作者： Tianyu Wei Pengcheng Zhou Wenxian Liu Xijun Liu Tairong Kuang Functional Polymers and Advanced Materials (FPAM) Lab Zhejiang Key Laboratory of Plastic Modification and Processing Technology College of Materials Science and Engineering Zhejiang University of Technology Hangzhou 310014 China State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures Guangxi Key Laboratory of Processing for Nonferrous Metals and Featured Materials MOE Key Laboratory of New Processing Technology for Nonferrous Metals and Materials School of Resources Environment and Materials Guangxi University Nanning 530004 China

The overuse and ineffective management of plastics have led to significant environmental pollution. Catalytic upcycling into value-added chemicals has emerged as a promising solution. This review provides a comprehensive overview of recent advances in catalytic upcycling, focusing on the cleavage of chemical bonds such as carbon-carbon (C-C), carbon-oxygen (C-O), and carbon-hydrogen (C-H) in plastics. It systematically discusses plastics conversion via electrocatalysis, thermal catalysis, and photocatalysis. Additionally, it explores the conversion of plastics into value-added chemicals and functional polymers. The review also addresses the challenges in this field and aims to offer insights for developing sustainable and effective plastics upcycling technologies.

关键词： plastics recycling catalysis chemical recycling value-added chemicals functional polymers

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Magnetic emission intensity enhancement for amorphous alloys by constructing a multi-phase structure withα-Fe nanocrystals

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Nano Research 2024年第7期17卷 6630-6637页

作者： Ke Liu Zhi Qin Jie Shen Zhi Cheng Shiyue You Liang Ma Jing Zhou Wen Chen State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China Sanya Science and Education Innovation Park Wuhan University of TechnologySanya 572024China Hubei Longzhong Laboratory Wuhan University of Technology Xiangyang Demonstration ZoneXiangyang 441000China

The perturbation in the magnetic field generated by the rotation or oscillation of magnetic domains in magnetic materials can emit low-frequency electromagnetic waves,which are expected to be used in low-frequency ***,the magnetic emission intensity,defined by the perturbation ability,of current commercially applied amorphous alloys,such as Metglas,cannot meet the application requirements for low-frequency antennas due to the domain motion energy ***,a multi-phase Metglas amorphous alloy was constructed by incorporatingα-Fe nanocrystals using rapid annealing to manipulate the domain *** was found that 3.89 times higher magnetic emission intensity is obtained compared to the pristine due to the synergism of the deformation and displacement ***,the low-frequency magnetic emission performance verification was carried out by preparing magnetoelectric composites as the antenna vibrator by assembling the alloy and macro piezoelectric fiber composites(MFC).Enhancements of magnetic emission intensity are found at 93.3%and 49.2%at the first and second harmonic frequencies compared with the unmodified alloy ***,the approach leads to the development of high-performance communication with a novel standard for evaluation.

关键词： multi-phase amorphous alloys magnetic emission intensity enhancing mechanism magnetic domain pinning theory Jiles-Atherton model analysis

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