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Design Engineering,synthesis Protocols,and Energy Applications of MOF-Derived Electrocatalysts

Nano-Micro Letters 2021年第9期13卷 16-47页

作者： Amr Radwan Huihui Jin Daping He Shichun Mu School of Science Wuhan University of TechnologyWuhan 430070People’s Republic of China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu Hydrogen ValleyFoshan 528200People’s Republic of China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070People’s Republic of China

The core reactions for fuel cells,rechargeable metal-air batteries,and hydrogen fuel production are the oxygen reduction reaction(ORR),oxygen evolution reaction(OER),and hydrogen evolution reaction(HER),which are heavily dependent on the efficiency of *** attempts have previously been devoted in non-noble electrocatalysts born out of metal-organic frameworks(MOFs)for ORR,OER,and HER applications,due to the following advantageous reasons:(i)The significant porosity eases the electrolyte diffusion;(ii)the supreme catalyst-electrolyte contact area enhances the diffusion efficiency;and(iii)the electronic conductivity can be extensively increased owing to the unique construction block subunits for MOFs-derived ***,the recent progress of MOFs-derived electrocatalysts including synthesis protocols,design engineering,DFT calculations roles,and energy applications is discussed and *** can be concluded that the elevated ORR,OER,and HER performances are attributed to an advantageously well-designed high-porosity structure,significant surface area,and plentiful active ***,the perspectives of MOF-derived electrocatalysts for the ORR,OER,and HER are presented.

关键词： MOF-derived electrocatalysis Oxygen reduction reaction Oxygen evolution reaction Hydrogen evolution reaction

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Structural and functional design of geopolymer adsorbents:a review

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Tungsten 2024年第1期6卷 48-76页

作者： Hai-Ze Jin Chen-Xi Qiu Yan-Song Li Bao Liu Jun-Yi Liu Qiao Chen Xue-Feng Lu Cui-Xia Li Qi-Kun Wang School of Materials Science and Engineering Lanzhou University of TechnologyLanzhou 730050China State Key Laboratory of Advanced Processing and Recycling of Non-Ferrous Metals Lanzhou 730050China Shenyang Nonferrous Metals Research Institute Co. LTDShenyang 110000China Automotive Engineering Research Institute Jiangsu UniversityZhenjiang 212013China School of Materials Science and Engineering Jingdezhen Ceramic UniversityJingdezhen 333403China

The water pollution derived from the discharge of heavy metals,antibiotics,dyes and surfactants wastewater,*** seriously affected human survival and ecological *** an efficient and low-cost physical wastewater treatment process,the adsorption is a continuous hot spot in related scientific research and *** are non-crystal or semi-crystalline materials with high-efficiency adsorption performance due to the alkali metal ions that balance the electronegative aluminosilicate skeleton can be efficiently replaced by other cations in the aqueous *** related studies of different application conditions,service objects and morphological differences of geopolymer adsorbents based on structure-function design have been in-depth exploration and *** review aims to summarize the research progres s of the structure-function design based on the geopolymerization mechanism and kinetics and service *** overview of service characteristics and progress of geopolymers in the wastewater treatment field(e.g.,dyes,heavy metals,radionuclides,surfactants,antibiotics,ammonium,phosphorus,nitrogen and CO_(2),etc.)are systematically *** the evolution and development of morphological differences and the relationship of structure-function design of geopolymer adsorbents were compared and ***,the challenge worth overcoming,the trends worth considering and perspectives worth developing are highlighted.

关键词： Geopolymer Wastewater Adsorption Structure-function design Application

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在导电陶瓷基体中加入hBN薄片来创制材料性能的各向异性

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Science China materials 2023年第11期66卷 4317-4325页

作者：梁华岳邹冀刘晶晶顾熠涵季伟王子涵王为民傅正义 Hubei Longzhong Laboratory Wuhan University of Technology Xiangyang Demonstration ZoneXiangyang 441000China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China Jingdezhen Huaxun Special Ceramics Co. Ltd.Jingdezhen 333000China

导电陶瓷的物理性能由连续的导电基体所决定,调控困难.在这项研究中,通过在陶瓷基体中引入hBN薄片,成功实现了导电陶瓷力学和物理性能各向异性的调控.以包含TiN、Al、硼和hBN的混合粉末为原料,通过放电等离子烧结制备了两种hBN含量不同... 详细信息

导电陶瓷的物理性能由连续的导电基体所决定,调控困难.在这项研究中,通过在陶瓷基体中引入hBN薄片,成功实现了导电陶瓷力学和物理性能各向异性的调控.以包含TiN、Al、硼和hBN的混合粉末为原料,通过放电等离子烧结制备了两种hBN含量不同的导电TiB_(2)-AlNhBN陶瓷.在垂直于烧结压力的方向上,TiB_(2)-AlN-60vol%hBN陶瓷在室温下的弯曲强度、断裂韧性、电导率和热导率分别为151±6.34MPa、2.62±0.31MPam^(1/2)、5.3×10^(5)S m^(−1)和77.87Wm^(-1)K^(-1).而在平行于烧结压力的方向上,室温电导率和热导率分别降低到2.0×10^(5)S m^(−1)和32.25Wm^(-1)K^(-1).这些差异是通过在导电基体中加入少量额外排列的hBN薄片而产生的,为材料选择和设计提供了新的机会.

关键词： hexagonal boron nitride texture microstructure mechanical property physical property

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Growth of magnetic metals on carbon microspheres with synergetic dissipation abilities to broaden microwave absorption

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Journal of materials Science & technology 2022年第12期107卷 100-110页

作者： Biao Zhao Yang Li Qingwen Zeng Bingbing Fan Lei Wang Rui Zhang Renchao Che Laboratory of Advanced Materials Shanghai Key Lab of Molecular Catalysis and Innovative MaterialsFudan UniversityShanghai 200438China Department of Materials Science Fudan UniversityShanghai 200438China Henan Key Laboratory of Aeronautical Materials and Application Technology School of Material Science and EngineeringZhengzhou University of AeronauticsZhengzhouHenan 450046China School of Material Science and Engineering Zhengzhou UniversityZhengzhouHenan 450001China State Key Laboratory of Solidification Processing Northwestern Polytechnical UniversityXi’an 710072China

Microwave absorption(MA) materials have been captured extensive attentions due to the serious electromagnetic(EM) pollution. Numerous interests focus on the MA performances of core-shell structural composites with magnetic constituents as cores and dielectric constituents as shells, which inevitably suppressed the magnetic coupling causing the decrease of magnetic loss to some extent. Herein, the coreshell structural carbon(C) microsphere/magnetic metal composites were fabricated through the combination of an electrostatic assembly approach and subsequent in-situ reduction reaction. The complex permittivity and permeability of core-shell C@magnetic metal composite system can be effective adjusted by the constituent and microstructure of shells. Thanks to the distinct magnetic coupling from the subtle designed structures and the promotion of the magnetic-dielectric synergy, the C@magnetic metal composite exhibited enhanced MA properties. The optimal reflection loss(RL) of C@Ni composite was-54.1 dB with a thickness of 3.4 mm, meanwhile the effective absorbing band could reach over 5.5 GHz at only a1.8 mm thickness. Broad absorption bandwidth with RL below-10 d B could achieve 6.0 GHz and 6.7 GHz for C@Co and C@Ni Co composites with a thin 2.1 mm thickness, respectively. Our exciting findings might lead a guide on the novel structure design for the functional core-shell structural composites used for microwave absorption.

关键词： Microwave absorption Core-shell structure C@magnetic metal composite Interfacial polarization Magnetic coupling

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Er:CaF2 Crystal and Laser Ceramic: a Comparative Study

Er:CaF2 Crystal and Laser Ceramic: a Comparative Study

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2024 advanced Solid state Lasers, ASSL 2024

作者： Normani, Simone Loiko, Pavel Gan, Shiyan Li, Weiwei Mei, Bingchu Benayad, Abdelmjid Jambunathan, Venkatesan Braud, Alain Chen, Weidong Camy, Patrice UMR 6252 CEA-CNRS-ENSICAEN Université de Caen Normandie 6 Boulevard Maréchal Juin Caen14050 Cedex 4 France State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou350002 China

Spectroscopy and mid-infrared laser performance are compared for Er:CaF2 single-crystal and hot-pressed transparent *** 2.8-µm Er:CaF2 crystal laser delivers 0.81 W with 32.6% slope efficiency and outperforms the... 详细信息

关键词： Single crystals

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Single-cell yolk-shell nanoencapsulation for long-term viability with size-dependent permeability and molecular recognition

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国家科学评论（英文版） 2021年第4期8卷 120-136页

作者： Li Wang Yu Li Xiao-Yu Yang Bo-Bo Zhang N(o)elle Ninane Henk J.Busscher Zhi-Yi Hu Cyrille Delneuville Nan Jiang Hao Xie Gustaaf Van Tendeloo Tawfique Hasan Bao-Lian Su State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan 430070 China Laboratory of Inorganic Materials Chemistry (CMI) University of Namur Namur B-5000 Belgium State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan 430070 China Laboratory of Inorganic Materials Chemistry (CMI) University of Namur Namur B-5000 Belgium Namur Research Institute for Life Sciences (Narilis) University of Namur Namur B-5000 Belgium Department of Biomedical Engineering University of Groningen and University Medical Centre Groningen Groningen 9713 AV The Netherlands State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan 430070 China Nanostructure Research Centre (NRC) Wuhan University of Technology Wuhan 430070 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan 430070 China School of Engineering and Applied Sciences Harvard University Cambridge MA 02138 USA Nanostructure Research Centre (NRC) Wuhan University of Technology Wuhan 430070 China Electron Microscopy for Materials Science (EMAT) University of Antwerp Antwerp B-2020 Belgium Cambridge Graphene Centre University of Cambridge Cambridge CB3 0FA UK

Like nanomaterials,bacteria have been unknowingly used for *** hold significant economic potential for fuel and medicinal compound *** full exploitation,however,is impeded by low biological activity and stability in industrial *** cellular encapsulation addresses these limitations,cell survival is usually compromised due to shell-to-cell contacts and low ***,we report ordered packing of silica nanocolloids with organized,uniform and tunable nanoporosities for single cyanobacterium nanoencapsulation using protamine as an electrostatic template.A space between the capsule shell and the cell is created by controlled internalization ofprotamine,resulting in a highly ordered porous shell-void-cell structure *** unique yolk-shell nanostructures provide long-term cell viability with superior photosynthetic activities and resistance in harsh *** addition,engineering the colloidal packing allows tunable shell-pore diameter for size-dependent permeability and introduction of new functionalities for specific molecular *** strategy could significantly enhance the activity and stability of cyanobacteria for various nanobiotechnological applications.

关键词： cell surface engineering protein internalization ordered colloidal packing high photosynthetic ability harsh condition resistance thiol-functionalization

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Multimaterial additive manufacturing manipulator for fabricating magnetoelectric pressure sensors

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Science China(Technological Sciences) 2022年第11期65卷 2542-2550页

作者： LIU ZhuFeng LI ZhaoQing WANG Qi WANG Yan YANG Lei NIE Xiang GENG Peng WU ZhenHua TANG SiHan YANG Lei WU HongZhi SHI YunSong CHEN Peng SU Bin ZHANG LiChao YAN ChunZe SHI YuSheng State Key Laboratory of Materials Processing and Die&Mould Technology Huazhong University of Science and Technology Wuhan 430074China State Key Laboratory of Advanced Electromagnetic Engineering and Technology Huazhong University of Science and TechnologyWuhan 430074China Schol of Materials Science and Enginering Wuhan Insitute of TechnologyWuhan 430205Chinai School of Transportation and Logisis Engineering Wuhan University of TechnologyWuhan 430063China Deparment of Orthopaedics Union HospitalTongji Medical CollegeHuazhong University of Science and Technology Wuhan 430030China

The simultaneous placement of different types of materials including polymers,ceramics,and metals,in their desired positions could be adopted to manufacture end-use devices/apparatuses with diverse functionalities and significantly reduce the fabrication cost and ***,existing additive manufacturing(AM)approaches can only treat one material species at a time due to their intrinsic working *** we develop an AM manipulator for manufacturing a wide variety of material species,including polymers,ceramics,and metals,through a multifilament transport strategy assisted by laser *** six-jaw manipulator contains three pairs of filament delivering/cutting systems for transporting diverse materials and a beam of tunable laser as the thermal *** whole apparatus is integrated into a robotic manipulator to create a multifreedom manufacturing *** this innovation,products with multiple material species and desired complex geometries can be fabricated on ***,we synthesize a multimaterial(polymer/ceramic/metal)printed magnetoelectric pressure sensor that can convert applied mechanical forces to electricity and maintain efficiency even after undergoing 10000 cycles of pressure/*** this multimaterial filament transport and laser manufacturing strategy,our AM manipulator exhibits promising application in the advanced manufacturing of embedded electronics,sensors,soft robotics,and customizable medical devices.

关键词： multiple materials additive manufacturing laser manipulator magnetoelectric

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Ultra-High-Performance Aluminum-Based Hybrid Supercapacitors Prepared for Nitrogen-Doped Micro-Mesoporous Carbon Sphere

SSRN

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SSRN 2023年

作者： Sun, Weiyi Xing, Lingli Zhang, Bomian Shi, Wenchao Ren, Jingke Zhang, Xinyu Xiong, Fangyu An, Qinyou State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Hubei Xiangyang441000 China

Aluminum-based devices are promising candidates for the next generation of energy storage due to the advantages of high energy density, high safety, and low cost. The aluminum ion batteries (AIBs) are based on the electrochemical intercalation/deintercalation reactions against the electrodes, but the selection of the cathode is limited to present. The cathode reactions of cation-type AIBs are plagued by the poor kinetics of solid-state diffusion from high charge density of Al3+ and anion-type AIBs show poor capacity due to the intercalation of large-sized chloroaluminate (AlCl4−) active ions into the cathode. Here, we deliberately adopted a hybrid capacitor-battery mechanism and employed a nitrogen-doped micro-mesoporous carbon sphere of a high specific area as the cathode and aluminum as the anode to construct an aluminum-based energy storage device. After optimization, it exhibits an excellent discharge capacity of 224 mA h g−1 at a current density of 300 mA g−1, and exceptional cycling performance with a discharge capacity as high as 114 mA h g−1 at 10 A g−1 after 35000 cycles. The ultra-high-performance aluminum-based hybrid supercapacitor (Al-HSC) may lead to a new direction for the development of aluminum-based energy storage devices. © 2023, The Authors. All rights reserved.

关键词： Aluminum

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Progress and perspectives in dielectric energy storage ceramics

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Journal of advanced Ceramics 2021年第4期10卷 675-703页

作者： Dongxu LI Xiaojun ZENG Zhipeng LI Zong-Yang SHEN Hua HAO Wenqin LUO Xingcai WANG Fusheng SONG Zhumei WANG Yueming LI Energy Storage and Conversion Ceramic Materials Engineering Laboratory of Jiangxi Province China National Light Industry Key Laboratory of Functional Ceramic MaterialsSchool of Materials Science and EngineeringJingdezhen Ceramic UniversityJingdezhen 333403China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China Chengdu Hongke Electronic Technology Co. Ltd.Chengdu 610000China

Dielectric ceramic capacitors,with the advantages of high power density,fast chargedischarge capability,excellent fatigue endurance,and good high temperature stability,have been acknowledged to be promising candidates for solid-state pulse power *** review investigates the energy storage performances of linear dielectric,relaxor ferroelectric,and antiferroelectric from the viewpoint of chemical modification,macro/microstructural design,and electrical property *** progress of ceramic bulks and films for Pb-based and/or Pb-free systems is ***,we propose the perspectives on the development of energy storage ceramics for pulse power capacitors in the future.

关键词： energy storage ceramics dielectric relaxor ferroelectric antiferroelectric pulse power capacitor

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Cobalt doping boosted electrocatalytic activity of CaMn3O6 for hydrogen evolution reaction

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Nano Research 2022年第4期15卷 2870-2876页

作者： Qun Li Kaisi Liu Siwei Gui Jiabin Wu Xiaogang Li Zaifang Li Hongrun Jin Hui Yang Zhimi Hu Wenxi Liang Liang Huang Wuhan National Laboratory for Optoelectronics Huazhong University of Science and TechnologyWuhan 430074China China-Australia Institute for Advanced Materials and Manufacturing Jiaxing UniversityJiaxing 314001China State Key Laboratory of Material Processing and Die&Mold Technology Department of MechanicsSchool of Aerospace EngineeringHuazhong University of Science and TechnologyWuhan 430074China

The development of earth-abundant-metal-based electrocatalysts with high efficiency and long-term stability for hydrogen evolution reaction(HER)is crucial for the clean and renewable energy ***,we report a molten-salt method to synthesize Co-doped CaMn_(3)O_(6)(CMO)nanowires(NWs)as effective electrocatalyst for *** as-obtained CaMn_(3-x)Co_(x)O_(6)(CMCO)exhibits a small onset overpotential of 70 mV,a required overpotential of 140 mV at a current density of 10 mA·cm^(-2),a Tafel slope of 39 mV·dec^(-1)in 0.1 M HClO_(4),and a satisfying long-term *** characterizations combined with density functional theory(DFT)calculations demonstrate that the obtained HER performance can be attributed to the Co-doping which altered CMO’s surface electronic structures and *** the simplicity of synthesis route and the abundance of the pertinent elements,the synthesized CMCO shows a promising prospect as a candidate for the development of earth-abundant,metal-based,and cost-effective electrocatalyst with superior HER *** results also establish a strategy of rational design and construction of novel electrocatalyst toward HER by tailoring band structures of transition metal oxides(TMOs).

关键词： CMCO nanowires hydrogen evolution reaction electronic structure dopant

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