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Groups-dependent phosphines as the organic redox for point defects elimination in hybrid perovskite solar cells

Journal of Energy Chemistry 2021年第3期30卷 23-29页

作者： Zhengli Wu Miao Zhang Yifan Liu Yuxi Dou Yinjie Kong Lin Gao Weitao Han Guijie Liang Xiao Li Zhang Fuzhi Huang Yi-Bing Cheng Jie Zhong State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070HubeiChina Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu Hydrogen ValleyFoshan 528200GuangdongChina Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices Hubei University of Arts and ScienceXiangyang 441053HubeiChina School of Materiale Science and Engineering Zhengzhou UniversityZhengzhou 450001HenanChina Department of Materials Science and Engineering Monash UniversityVIC 3800Australia

Lead(Pb)^(0) and iodine(I)^(0) point defects generated during perovskite solar cell(PSC)fabrication and photoconversion form deep band energy levels as the carriers’recombination *** defects not only deteriorate device efficiency,but also facilitate chemical degradation with ion migration,resulting in restricted device ***,we present a novel type of phosphines as the point defects stabilizer for hybrid perovskite solar cells with enhanced *** phosphines with varied side groups of tributyl,trioctyl and triphenyl are exampled as the dopants in perovskite *** group dependent redox properties were observed in the perovskite film,dependent on their molecular weights and steric hinderances of *** partially oxidized tributyl phosphine(TBUP)with additional tributyl phosphine oxides(TBPO)is efficient in reduction of lead(Pb)^(0) and iodine(I)^(0) concentrations during the device fabrication and *** device with TBUP-TBPO pair showed enhanced power conversion efficiency(PCE)to 20.48% and maintain 91.7% of their initial PCEs after 500 h at 65℃ thermal ***,this work presents an efficient route of utilize the phosphine species to reduce point defects in the perovskite film,which promoting further development of novel phosphorous additives with defects stabilization,interface passivation and encapsulation for low-cost solution processed PSCs.

关键词： Redox Perovskite solar cells Phosphine organics Lead defect Stability

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Harnessing the enol/keto-form emission of ESIPT: mechanochromism, multi-channel imaging, and detection of a chemical warfare agent mimic

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Science China materials 2025年第2期68卷 448-454页

作者： Kangmin Wang Min Zhang Danni Yang Liqiu Wan Shouxin Zhang Liang Yan Ke Yang Bijin Li Chongqing Key Laboratory of Natural Product Synthesis and Drug Research School of Pharmaceutical Sciences&Department of Medical LaboratoryShapingba Hospital Affiliated to Chongqing UniversityChongqing UniversityChongqing 401331China State Key Laboratory of NBC Protection for Civilian Beijing 100191China Jiangsu Key Laboratory of Advanced Catalytic Materials&Technology School of Petrochemical EngineeringChangzhou UniversityChangzhou 213164China

Reported herein is the first time mechanochromicmaterials based on sole enol-form emission of 2-(2’-hydroxyphenyl)azoles containing one triphenylamine (TPA).Three different single crystals were obtained and representpristine, intermediate, and ground states, respectively. The 2-(2’-hydroxyphenyl)azoles containing two TPA exhibit balanced dual-emission and could be used in multi-channelimaging, and selectivity accumulated in mitochondria of livingcells. In addition, we developed the first example of excitedstate intramolecular proton transfer (ESIPT) materials withsole enol-form emission and balanced dual-emission to detectchemical warfare agents (CWAs) mimic diethyl chlorophosphate (DCP) with good selectivity, highly sensitive, and fastresponsive.

关键词： fluorescent materials enol-form emission keto-form emission ESIPT chemical warfare agents

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The staggered-layer induced elasticity strengthening mechanism in flexible Bi2Te3

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Matter 2025年

作者： Huang, Xiege Wu, Luoqi Hu, Mingyuan Feng, Xiaobin Zhai, Pengcheng Li, Wenjuan Duan, Bo He, Jiaqing Li, Guodong Zhang, Qingjie Goddard, William A. Hubei Key Laboratory of Theory and Application of Advanced Materials Mechanics School of Physics and Mechanics Wuhan University of Technology Wuhan430070 China Guangdong Provincial Key Laboratory of Advanced Thermoelectric Materials and Device Physics Shenzhen Key Laboratory of Thermoelectric Materials and Department of Physics Southern University of Science and Technology Shenzhen518055 China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Materials and Process Simulation Center California Institute of Technology PasadenaCA91125 United States

Wearable flexible devices require the development of thermoelectric (TE) materials with high strength, excellent elastic bendability, and superior ductility. Here we report a staggered-layer strategy that overcomes the strength-flexibility dilemma. Our findings indicate that the newly formed strong Bi–Bi covalent bond between the staggered layer leads to an average 40% increase in the bond energy of the van der Waals Te–Te bond. A large Poisson's ratio leads to a high maximum linear elastic strain (ΕEmax), enhancing shear strength by 83.3%, which is consistent with a 92.2% increase in micro-pillar compressive strength. The narrow stiffness gap and bond energy gap facilitate the coordinated deformation that maintains sustained linear elasticity during compression. Moreover, the low BFCs of the Te–Te and Te–Bi bonds (0.72 eV/Å2 and 3.85 eV/Å2) contribute to the experimentally observed bending flexibility. This staggered-layer-induced elasticity strengthening mechanism offers a promising strategy for the rational design of highly reliable wearable TE devices. © 2025 Elsevier Inc.

关键词： Compressive strength

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Synergistic Regulation of Texture and Low-Angle Grain Boundaries Enables Mechanically Robust P-Type Bi2Te3- Based Compounds with Superior Thermoelectric Performance

SSRN

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SSRN 2024年

作者： Chen, Shuo Luo, Tingting Li, Junjie Liao, Lin Liu, Yutian Yang, Zhen Zhong, Shenlong Wu, Jinsong Su, Xianli Yan, Yonggao Poudeu, Pierre Ferdinand Poudeu Zhang, Qingjie Tang, Xinfeng State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Department of Materials Science and Engineering University of Michigan at Ann Arbo Ann ArborMI48109 United States

Structural material parameters such as grain size, texture, and grain boundary species play crucial roles in anisotropic thermoelectric materials. In this study, the underlying mechanism for rational regulation of grain size, texture, and grain boundary species is uncovered. The variations in the plastic deformation capability and the atomic diffusion rates at different extrusion temperatures lead to a competition between dynamic recrystallization (DRX) and grain growth, which allows for quantitative regulation over grain size, texture, and low-angle grain boundaries (LAGBs) in the material. As a result, grain size can be effectively tuned from the nanometer scale to the micrometer scale, with the orientation factor F(110) adjusting from 0.23 to 0.41, and the concentration of LAGBs varying between 10.9% and 25.2%. The sample extruded at 673 K exhibits an average grain size of 800 nm, which contribute to the observed compressive strength of 226 MPa and bending strength of 126 MPa. Additionally, the high texture and high density of LAGBs ensure a high carrier mobility of 247 cm2 V-1 s-1. The ZT value of 1.2 enables micro-TEC modules and conventional TEC modules to achieve maximum temperature differences (ΔTmax) of 60 K and 78 K, respectively, at the hot-side temperature of 300 K. © 2024, The Authors. All rights reserved.

关键词： Compressive strength

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Structure and Tribological Evolution of Ta-N Layer by Controlling the Time of Microwave Plasma Nitriding

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SSRN 2024年

作者： Li, Jiacheng Xu, Zhigang Peng, Jian Shen, Qiang Wang, Chuanbin State Key Lab of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China Chaozhou Branch of Chemistry and Chemical Engineering Guangdong Laboratory Guangdong Chaozhou521000 China

The Ta-N layer on the Ta matrix surface was synthesized using microwave plasma nitriding (MPN) to enhance its wear resistance. The effects of holding time on the phase composition, morphology, mechanical properties, friction, and wear of the nitriding layers were systematically examined. The results revealed that nanocrystalline Ta-N layers with a dense surface and low roughness were successfully fabricated. The thickness of the Ta-N layer increased from 0.87 μm to 4.23 μm with prolonged holding time. The hardness of the Ta-N layer increased first and then decreased with the extension of holding time, and reached the maximum at 4h. Friction and wear test results indicated that the Ta-N layer exhibited superior wear resistance at the holding time of 4 h, which was mainly attributed to the synergy of dense structure and the generation of the nanocrystal. In conclusion, the Ta-N layer with the desired hardness and wear resistance was obtained due to MPN treatment, which offered excellent surface protection for the Ta matrix in terms of wear resistance. © 2024, The Authors. All rights reserved.

关键词： Nanocrystals

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Aromaticity Concerto in Polycyclic Conjugated Hydrocarbons:Fusion Pattern on Combined Aromaticity Strategy Leads to Distinctive Excited state Photophysics of Dinaphthopentalenes

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CCS Chemistry 2023年第10期5卷 2264-2276页

作者： Long Wang Lu Lin Teng-Shuo Zhang Shaoting Guo Zuyuan Liu Mengfan Zhang Senhao Wang Ganglong Cui Wei-Hai Fang Jun Zhu Hongbing Fu Jiannian Yao Key Laboratory of Interface Science and Engineering in Advanced Materials Ministry of EducationCollege of ChemistryTaiyuan University of TechnologyTaiyuan 030024 State Key Laboratory of Physical Chemistry of Solid Surfaces Fujian Provincial Key Laboratory of Theoretical and Computational ChemistryDepartment of ChemistryCollege of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005 State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology College of Chemical EngineeringZhejiang University of TechnologyHangzhou 310014 Key Laboratory of Theoretical and Computational Photochemistry Ministry of EducationCollege of ChemistryBeijing Normal UniversityBeijing 100875 Beijing Key Laboratory for Optical Materials and Photonic Devices Department of ChemistryCapital Normal UniversityBeijing 100048 Beijing National Laboratory for Molecules Science Key Laboratory of PhotochemistryInstitute of ChemistryChinese Academy of SciencesBeijing 100190

Understanding the structure-property relationships in polycyclic conjugated hydrocarbons(PCHs)is crucial in controlling their electronic properties and developing new optically functional *** is a fundamentally important and intriguing property of numerous organic chemical structures and has stimulated a myriad of experimental and theoretical *** aromaticity rules for the rational design of optoelectronic materials with the desired photophysical characteristics is a challenging yet fascinating *** we present an in-depth computational and spectroscopic study on the structure-property relationships of dinaphthopentalenes(DNPs).Results highlight that the different fusion patterns between 4nπand 4n+2πunits endow these PCHs with the tunable aromaticity in the ground state/excited state,which leads to the diverse electronic structures and consequently the distinctive excited state ***,we propose a combined aromaticity design strategy for rationally modulating and tailoring electronic and optical properties of PCH *** outcomes not only present a full picture of the excited state dynamics of the DNP system and afford a new class of efficient singlet fission-active materials but also provide some basic guidelines for exploiting aromaticity rules to design and develop new optical function materials.

关键词： polycyclic conjugated hydrocarbon aromaticity fusion pattern excited state photophysics singlet fission combined aromaticity design strategy optical function materials

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A Strategy to Reduce the Peak Temperature of the Chip Working under Dynamic Power Using the Transient Cooling Effect of the Thin-Film Thermoelectric Cooler

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Journal of Thermal Science 2022年第4期31卷 1094-1105页

作者： WU Yongjia CHEN Sen GONG Tingrui SHI Tianhao ZUO Lei YAN Yonggao FANG Yueping MING Tingzhen School of Civil Engineering and Architecture Wuhan University of TechnologyWuhan 430070China Microsystem&Terahertz Research Center China Academy of Engineering PhysicsChengdu 610200China Department of Mechanical Engineering Virginia TechBlacksburgVA 24060USA State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China School of Energy Construction and Environment Coventry UniversityCoventry CV15FBUK

The thin-film thermoelectric cooler(TEC)is a promising solid-state heat pump that can remove the high local heat flux of chips utilizing the Peltier *** an electric current pulse is applied to the thin-film TEC,the TEC can achieve an instantaneous lower temperature compared to that created by a steady *** this paper,we developed a novel strategy to reduce the peak temperature of the chip working under dynamic power,thus making the semiconductor chip operate reliably and efficiently.A three-dimensional numerical model was built to study the transient cooling performance of the thin-film TEC on *** effects of parameters,such as the current pulse,the heat flux,the thermoelement length,the number of thermoelements,and the contact resistance on the performance of the thin-film TEC,were *** results showed that when a current pulse of 0.6 A was applied to the thin-film TEC before the peak power of the chip,the peak temperature of the chip was reduced by more than 10℃,making the thin-film thermoelectric cooler a promising technology for the temperature control of modern chips with high peak powers.

关键词： temperature control transient cooling thermoelectric cooler heat transfer

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Hetero-phase MoC-Mo_(2)C nanoparticles for enhanced photocatalytic H_(2)-production activity of TiO_(2)

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Nano Research 2021年第4期14卷 1095-1102页

作者： Jinfeng Liu Ping Wang Jiajie Fan Huogen Yu Jiaguo Yu School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China School of Chemistry Chemical Engineering and Life SciencesWuhan University of TechnologyWuhan 430070China School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450002China State Key Laboratory of Advanced Technology for Material Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

Hexagonal molybdenum carbide(Mo_(2)C)as an effective non-noble cocatalyst is intensively researched in the photocatalytic H_(2)-evolution field owing to its Pt-like H^(+)-adsorption ability and good ***,hexagonal Mo_(2)C-modified photocatalysts possess a limited H_(2)-evolution rate because of the weak H-desorption *** improve the activity,cubic MoC was introduced into Mo_(2)C toform the carbon-modified MoC-Mo_(2)C nanoparticles(MoC-Mo_(2)C@C)by a calcination *** resultant MoC-Mo_(2)C@C(ca.5 nm)was eventually coupled with Ti0_(2)to acquire high-efficiency Ti0_(2)/MoC-Mo_(2)C@C by electrostatic *** highest H_(2)-generation rate of Ti0_(2)/MoC-Mo_(2)C@C reached of 918μmol·h^(-1)·g^(-1)which was 91.8,2.7,and 1.5 times than that of the Ti0_(2),TiO_(2)/MoC@C,and Ti0_(2)/Mo_(2)C@C,*** enhanced rate of Ti0_(2)attributes to the carbon layer as cocatalyst to transmit electrons and the hetero-phase MoC-Mo_(2)C as H_(2)-generation active sites to boost H_(2)-evolution *** research offers a novel insight to design photocatalytic materials for energy applications.

关键词： TiO_(2) MoC-MO_(2)C@C cocatalyst H_(2)evolution photocatalysis

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Mesoporous carbon layer encapsulated SnSe nanosheets via covalent bonds for high-performance sodium ion batteries

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ChemPhysMater 2023年第2期2卷 164-171页

作者： Mengfei Wang Liang Yang Maocheng Liu School of Mechanical and Electrical Engineering Lanzhou University of TechnologyLanzhou 730050China State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals Lanzhou University of TechnologyLanzhou 730050China School of Materials Science and Engineering Lanzhou University of TechnologyLanzhou 730050China

Sodium ion batteries(SIBs)have been widely studied because of their low cost,low standard redox potential,and abundant sodium ***,the structural rupture during the Na+insertion/extraction processes and the poor conductivity of the anode material limit its cycling stability and rate ***,SnSe@C was prepared by high-temperature annealing with dopamine hydrochloride as the carbon source,while SnSe was prepared by a protein reduction *** carbon layer not only works as a protective layer to limit the volume expansion of SnSe and reduce the dissolution of Na 2 Se and poly-selenides generated during the discharge process in the electrolyte,but also as a conductive matrix to expedite electron transfer,thereby boosting the cycling stability and rate capability of SnSe@*** from the above advantages,SnSe@C exhibits a specific capacity of 211.3 mAh g^(−1) at 0.1 A g^(−1) after 110 cycles and outstanging rate capability(210.1 mAh g^(−1) at 5.0 A g^(−1) and capacity retention rate of 63.2%from 0.1 to 1.0 A g^(−1)).This study not only proposes an idea for promoting the cycling stability and rate capability of SnSe,but also paves the way for providing anodic materials with a stable structure for SIBs.

关键词： Sodium ion batteries Protein reduction method SnSe nanosheets High conductivity

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Compressive deformation-induced hierarchical microstructure in a TWIPβTi-alloy

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Journal of materials Science & technology 2022年第17期112卷 130-137页

作者： Jinyong Zhang Bingnan Qian Wang Lin Ping Zhang Yijin Wu Yangyang Fu Yu Fan Zheng Chen Jun Cheng Jinshan Li Yuan Wu Yu Wang Fan Sun School of Materials and Physics China University of Mining and TechnologyXuzhou 221116China State Key Laboratory of Solidification Processing Northwestern Polytechnical UniversityXi’an 710072China State Key Laboratory for Advanced Metals and Materials University of Science and Technology BeijingBeijing 100083China Chimie ParisTech-CNRS Institut de Recherche de Chimie ParisPSL Research UniversityParis 75005France Shaanxi Key Laboratory of Biomedical Metal Materials Northwest Institute for Non-ferrous Metal ResearchXi’an 710016China Beijing General Research Institute of Mining and Metallurgy Beijing 102206China

The deformation mode of{332}twinning(hereafter called 332T)has often been observed under the plastic flow in metastableβtitanium alloys with body-centered cubic(BCC)structure,which contributes to improving the mechan... 详细信息

The deformation mode of{332}<113>twinning(hereafter called 332T)has often been observed under the plastic flow in metastableβtitanium alloys with body-centered cubic(BCC)structure,which contributes to improving the mechanical ***,we report a structure of compressive deformation-induced primary 332T with hierarchical and/or heterogeneous composite sub-structure in a Twin-Induced Plasticity(TWIP)βTi-alloy under uniaxial *** detailed structural characterization after compressive deformation revealed that the sub-structure,including secondary 332T and secondary{112}<111>twinning,formed inside the 332T structure,which constitutes a hierarchical and/or heterogeneous structure at micro-and nano-scale and consequently contributes to the high strength,large ductility and enhanced strain-hardening behavior.

关键词： MetastableβTi-alloys TWIP effects Compression deformation behavior Microstructural characterization

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