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Bottom-up synthesis of 2D heterostructures enables effective polysulfides inhibition and conversion

Nano Research 2023年第6期16卷 8488-8496页

作者： Ge Zhang Cheng Zhou Juncai Long Yan Li Lei Lv Kaijian Yan Xinhui Chen Chenxu Dong Xu Xu Liqiang Mai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China International School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China

Due to the high theoretical capacity and energy density,lithium-sulfur(Li-S)batteries have good commercial ***,shuttle effect of soluble lithium polysulfides(LiPSs)formed by sulfur reduction has severely limited the further development of Li-S *** this work,the two-dimensional(2D)MXene-metal-organic framework(MOF)(Ti_(3)C_(2)T_(x)-CoBDC(BDC:1,4-benzenedicarboxylate))heterostructures were employed to modify the separator to inhibit the shuttle effect and facilitate the conversion of the soluble ***,a bottom-up synthesis strategy was adopted to synthesize the 2D MXene-MOF heterogeneous layered *** high specific surface area,in which the catalytic metal atoms not only restrain the shuttle effect of polysulfides but also exhibit excellent redox electrocatalytic *** cell with Ti_(3)C_(2)T_(x)-CoBDC@PP(PP:polypropylene)separator has a high initial capacity of 1255 mAh·g^(−1)at 0.5 *** the current density is 2 C,the battery has a capacity retention rate of 94.4%after 600 cycles,with the fading rate of only 0.01%per ***,with a sulfur loading of 7.5 mg·cm^(−2),the battery shows the discharge capacity of 1096 mAh·g^(−1)at 0.2 C and exhibits excellent cycling *** work offers novel insights into the application of MOF and MXene heterostructures in Li-S batteries.

关键词： nanosheets lithium-sulfur batteries MXenes modified separators shuttle inhibition

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Energy-dispersive X-ray Spectroscopy for the Quantitative Analysis of Pyrite Thin Specimens

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Journal of Wuhan University of technology(Materials Science) 2023年第6期38卷 1304-1310页

作者： LUO Tingting GUO Yi DENG Zhao LIU Xiaoqing SUN Zhenya QI Yanyuan YANG Meijun Center for Materials Research and Analysis Testing Wuhan University of Technology Wuhan 430070China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070Wuhan

To explore ways to improve the accuracy of quantitative analysis of samples in the micrometer to nanometer range of magnitudes,we adopted analytical transmission electron microscopy(AEM/EDS)for qualitative and quantitative analysis of pyrite ***,the k factor of pyrite is calculated *** develop an appropriate non-standard quantitative analysis model for pyrite materials,the experimentally calculated k factor is compared with that estimated from the non-standard quantitative analytical model of the instrument *** experimental findings demonstrate that the EDS attached to a TEM can be employed for precise quantitative analysis of micro-and nanoscale regions of pyrite ***,it serves as a reference for improving the results of the EDS quantitative analysis of other sulfides.

关键词： analytical transmission electron microscopy(AEM) energy dispersive X-ray spectroscopy(EDS) pyrite thin specimen quantitative analysis

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Molecular Engineering of g-C_(3)N_(4)with Dibenzothiophene Groups as Electron Donor for Enhanced Photocatalytic H_(2)-Production

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Chinese Journal of Structural Chemistry 2022年第6期41卷 48-54页

作者： Shanren Tao Sijie Wan Qinyang Huang Chengming Li Jiaguo Yu Shaowen Cao State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

The construction of donor-acceptor(D-A)molecular structure is an attractive strategy to enhance the photocatalytic performance of polymeric ***,dibenzothiophene(DBT)-4-carbaldehyde as the precursor is introduced into g-C_(3)N_(4)(TCN)prepared by two-step thermal polymerization to construct an intramolecular D-A type copolymer(TCN-DBT_(x)).DFT calculation and experimental results reveal that DBT plays the role of electron donor unit to modify g-C_(3)N_(4).The incorporation of DBT not only adjusts the band gap to improve reduction ability,but also induces an internal electric field with extendingπ-conjugated system for effective charge *** a result,TCN-DBT_(x)exhibits much better photocatalytic performance with an optimal hydrogen production rate of 3334μmol h^(-1)g^(-1),which is 2.5 times that of *** work provides a protocol for preparing high-performance g-C_(3)N_(4)-based photocatalysts toward various applications.

关键词： carbon nitride donor-acceptor photocatalysis charge transfer

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Microstructure and Mechanical Property of (TiNbTaZrHf)C Synthesized by In-situ Reaction

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Journal of Wuhan University of technology(Materials Science) 2022年第2期37卷 177-183页

作者： ZHOU Qing ZHANG Jinyong FU Zhengyi WANG Dangqiang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

The(TiNbTaZrHf)C high entropy carbide(HEC)was successfully synthesized by complete commercial transition metal powders,obtained fine sintered bulks without additives by in-situ reaction element synthesis method.(TiNbTaZrHf)C bulk shows a face centered cubic rock salt structure with homogeneous single-phase FCC structure in composition and *** optimum sintering temperature is about 1900℃at which the best mechanical properties are *** mechanical properties of(TiNbTaZrHf)C ceramic block are better than those of binary transition metal carbides,and it has obvious high entropy *** a small amount of Al as sintering additive,the mechanical properties of(TiNbTaZrHf)C ceramics continue to improve,the bending strength of the samples at each temperature is increased by at least 38%,and the highest is 486 *** elastic modulus and hardness of the sample at 1900℃are also slightly increased by 4%and 14%,*** above conclusions illustrate that the properties of high entropy ceramics are greatly improved by in-situ reaction sintering.

关键词： high entropy carbide in-situ reaction microstructure mechanical property sintering additive

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Isomeric Fluorene-based Heteroundecenes with Different Side Chains Anchoring Positions for Small Molecule Acceptors

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Journal of Wuhan University of technology(Materials Science) 2022年第1期37卷 136-147页

作者： WANG Wei ZHAN Chun XIAO Shengqiang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

Two isomeric fluorene-based heteroundecenes of bis(thienocyclopenthieno[3,2-b]thieno)fluorene(BT2T-F)and bis(dithieno[3,2-b:2’,3’-d]thiophene)cyclopentafluorene(B3T-F)have been designed and *** side chains of 4-hexylphenyl anchor on the 5th and 8th positions in B3T-F while on the 4th and 9th positions in BT2T-F,in which the former is closer to the center of the fused *** corresponding acceptor-donor-acceptor(A-D-A)type small molecule acceptors(SMAs)of BT2T-FIC and B3T-FIC were prepared by linking BT2T-F and B3T-F as fused ring donor units with the acceptor unit of 2-(5,6-difluoro-3-oxo-2,3-dihydroinden-1-ylidene)malononitrile(IC-2F),respectively.B3T-FIC presents a superior crystallinity with intense face-on π-π stacking in its neat film while BT2T-FIC is more *** blended with PBDB-T-2Cl as a polymer donor,the optimized PBDB-T-2Cl:BT2T-FIC device exhibits an averaged power conversion efficiency(PCE)of 10.56%while only 7.53%in the PBDB-T-2Cl:B3T-FIC *** improved short-circuit current(J_(sc))and fill factor(FF)of the PBDB-T-2Cl:BT2T-FIC device are the main contribution of its higher performance,which is attributed to its more efficient and balanced charge transport and better carrier recombination *** that BT2T-FIC blend and B3T-FIC blend films both take a preferential face-on orientatedπ-πstacking with comparable distances,the suitable SMA domain size obtained in the BT2T-FIC blend could account for its more efficient photovoltaic *** results highlight the importance of side-chain strategy in developing efficient SMAs with huge fused ring cores.

关键词： polymer solar cells small molecule acceptor side chains morphology

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Bioresponsive fluorescent probes active in the second near-infrared window

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iRADIOLOGY 2023年第1期1卷 36-60页

作者： Yuqin Chen Jie Chen Baisong Chang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhanChina

Emerging stimuli-responsive composite probes active in the second nearinfrared window(NIR-II,1000–1700 nm)hold vast potential for improving in vivo imaging performance with minimized noise *** interactions among external irradiation,shell species,and the emissive core are key factors in the design of smart *** external irradiation provides energy for shell species and the emissive core to generate intense NIR-II fluorescence signals,while the energy transfer process hinders NIR-II emission in the inner structure of smart composite ***,if pathophysiological stimuli interrupt the above processes,then NIR-II fluorescence signals are *** review covers NIR-II imaging based on diverse smart composite NIR-II fluorescent probes responding to various biological stimuli,including ONOO−,overexpressed reactive sulfur species,abnormally expressed enzymes,and abnormal levels of physiological ***,to appreciate these advances,the challenges and perspectives of stimuliresponsive composite NIR-II probes are highlighted.

关键词： composite engineering second near-infrared window smart probe stimulus sensitivity pathophysiological microenvironment

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Yolk-shell FeSe_(2)@CoSe_(2)/FeSe_(2) heterojunction as anode materials for sodium-ion batteries with high rate capability and stability

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Journal of Materials Science & technology 2024年第5期172卷 185-195页

作者： Liuyang Zhang Bicheng Zhu Difa Xu Zibao Qian Ping Xie Tao Liu Jiaguo Yu Laboratory of Solar Fuel Faculty of Materials Science and ChemistryChina University of GeosciencesWuhan 430078China Hunan Key Laboratory of Applied Environmental Photocatalysis Changsha UniversityChangsha 410022China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

Sodium-ion batteries are promising candidates for large-scale grid storage systems and other *** foremost advantage derives from superior environmental credentials,enhanced safety as well as lower raw material costs than lithium-ion *** is still challenging to explore desirable anode *** this study,FeSe_(2)@CoSe_(2)/FeSe_(2),with a yolk-shell structure was prepared by ion exchange and *** FeSe_(2)@CoSe_(2)/FeSe_(2)prepared as anode material for sodiumion batteries exhibits excellent rate capability due to the synergistic effect of bimetallic selenides and the interfacial effect of the ***,it delivers high performance(510 mAh g^(-1)at 0.2 A g^(-1)),superior rate capa-bility(90%retention at 5 A g^(-1)),and good long-time cycling stability(78%capacity retention after 1800 cycles at a high current density of 2 A g^(-1)).The optimized sodiumion full cell with FeSe_(2)@CoSe_(2)/FeSe_(2)as the anode and Na 3 V 2(PO 4)3 as the cathode still demonstrates excellent ***,a ca-pacity of 272 mAh g^(-1)(at 1 A g^(-1))within the operating voltage from 1 to 3.8 V can be *** work illustrates the potential of bimetallic selenides with heterostructures for performance enhancement of sodium-ion batteries.

关键词： Cobalt-iron selenide Heterojunctions Sodium storage Anode material Full battery

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Exploring photogenerated charge carrier transfer in semiconductor/metal junctions using Kelvin probe force microscopy

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Journal of Materials Science & technology 2024年第6期173卷 11-19页

作者： Chuanbiao Bie Zheng Meng Bowen He Bei Cheng Gang Liu Bicheng Zhu Laboratory of Solar Fuel Faculty of Materials Science and ChemistryChina University of GeosciencesWuhan 430078China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China CAS Key Laboratory of Standardization and Measurement for Nanotechnology National Center for Nanoscience and TechnologyBeijing 100190China

Semiconductor/metal junctions are widely discussed in ***,there is a notable scarcity of systematic studies focusing on photogenerated charge carrier transfer in such ***,CdS/Pt,CdS/Au,and CdS/Ag are synthesized to serve as model systems for investigating the charge carrier transfer in semiconductor/metal *** probe force microscopy is employed to visualize the transfer of photogenerated carriers in these *** results show that the electron transfer behavior under illumination is related to the conduction band position of CdS and the Fermi level position of the ***,Schottky junctions hinder the transfer of photogenerated electrons from CdS to Pt and Au,whereas ohmic contacts facilitate the transfer of photogenerated electrons from CdS to *** work provides novel insights into the mechanisms governing the transfer of photogenerated carriers in semiconductor/metal junctions.

关键词： Kelvin probe force microscopy Surface potential Work function Contact potential difference Charge carrier transfer

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Imaging-guided precision oncotherapy mediated by nanoprobes: From seeing to curing

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Chinese Chemical Letters 2024年第1期35卷 116-128页

作者： Jie Zheng Shi-Hui Chen Biao Huang Mingxi Zhang Quan Yuan Ran Cui College of Chemistry and Molecular Sciences Wuhan UniversityWuhan 430072China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Hubei Jiangxia Laboratory Wuhan 430200China

Malignant tumors are the main diseases threatening human life. Using precise theranostics to diagnose and cure tumors has emerged as a new method to improve patient survival. Based on the current development of precise tumor imaging, image-guided tumor therapy has received widespread attention because it is beneficial for developing precise treatment of tumors, has the potential to improve the efficacy of tumor therapy and reduce the incidence of adverse side effects. Nanoprobes, which are nanomaterial functionalized with specific biomolecules, have intrigued intense interest due to their great potential in monitoring biorecognition and biodetection evens. Benefiting from the unique advantages of nanomaterials, including the easy surface functionalization, the unique imaging performances, and the high drug loading capacity, nanoprobes have become a powerful tool to simultaneously realize tumor precise imaging, diagnosis, and therapy. This review introduces the non-invasive tumor precise imaging and highlights the recent advances of image-guided oncotherapy mediated by nanoprobes in anti-tumor drug delivery, tumor precise surgical navigation, chemodynamic therapy, and phototherapy. Finally, a perspective on the challenge and future direction of nanoprobes in imaging-guided tumor theranostics is also discussed.

关键词： Precise theranostics Imaging-guided Tumor surgical navigation Chemodynamic therapy Phototherapy Nanoprobes

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Review and prospects on the low-voltage Na_(2)Ti_(3)O_(7) anode materials for sodium-ion batteries

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Journal of Energy Chemistry 2024年第1期88卷 446-460,I0011页

作者： Jun Dong Yalong Jiang Ruxing Wang Qiulong Wei Qinyou An Xiaoxing Zhang Hubei Key Laboratory for High-efficiency Utilization of Solar Energy and Operation Control of Energy Storage System Hubei University of TechnologyWuhan 430068HubeiChina State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhan 430200HubeiChina Xiamen Key Laboratory of High-Performance Metals and Materials College of MaterialsXiamen UniversityXiamen 361005FujianChina State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070HubeiChina

Due to its low cost and natural abundance of sodium,Na-ion batteries(NIBs)are promising candidates for large-scale energy storage *** development of ultralow voltage anode materials is of great significance in improving the energy density of ***-voltage anode materials,however,are severely lacking in *** all the reported insertion oxides anodes,the Na_(2)Ti_(3)O_(7) has the lowest operating voltage(an average potential of 0.3 V ***^(+)/Na)and is less likely to deposit sodium,which has excellent potential for achieving NIBs with high energy densities and high *** significant progress has been made,achieving Na_(2)Ti_(3)O_(7) electrodes with excellent performance remains a severe *** paper systematically summarizes and discusses the physicochemical properties and synthesis methods of Na_(2)Ti_(3)O_(7).Then,the sodium storage mechanisms,key issues and challenges,and the optimization strategies for the electrochemical performance of Na_(2)Ti_(3)O_(7) are classified and further ***,remaining challenges and future research directions on the Na_(2)Ti_(3)O_(7) anode are *** review offers insights into the design of high-energy and high-safety NIBs.

关键词： Sodium-ion batteries Low-voltage anode materials Na_(2)Ti_(3)O_(7) Electrochemical performances Electrochemical mechanism

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